Microstructure and corrosion property evolution of a surface-nanostructured 15-15Ti austenitic steel during immersion in liquid LBE at 550 °C

被引:0
|
作者
Wang, Da [1 ]
Zhuo, Weiqian [2 ]
Liu, Sirui [1 ]
Xiao, Changquan [1 ]
Zhu, Wenjian [1 ]
Sun, Bihan [1 ]
Ma, Xianfeng [1 ]
Yuan, Ganfeng [1 ]
Sun, Yulin [1 ]
机构
[1] Sun Yat Sen Univ, Sino French Inst Nucl Engn & Technol, Zhuhai 519082, Peoples R China
[2] Nucl Power Inst China, Sci & Technol Reactor Fuel & Mat Lab, Chengdu 610213, Peoples R China
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
Austenitic steel; Nano-crystallization; Recrystallization; Lead-bismuth eutectic; Corrosion; FERRITIC-MARTENSITIC STEEL; BI EUTECTIC ALLOY; STAINLESS-STEEL; OXIDATION BEHAVIOR; HIGH-TEMPERATURE; 316L; OXYGEN; DISSOLUTION; RESISTANCE; MECHANISM;
D O I
10.1016/j.jnucmat.2024.155475
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This study investigated the compatibility of surface-nanostructured 15-15Ti austenitic steel in 550 degrees C LBE with an oxygen concentration of 5 x 10(-7) wt.% for various exposure durations (759, 1638, 2404, and 3012 h). The results demonstrate that the grain size was reduced from 33.50 mu m to the nano-scale after shot-peening (SP), achieving 17.62, 15.44, and 14.25 nm under SP pressures of 0.06, 0.15 and 0.25 MPa, respectively. The untreated steel experienced severe oxidation and dissolution corrosion, whereas the surface-nanostructured steel exhibited only mild oxidation and was resistant to dissolution corrosion. The enhanced corrosion resistance of surface-nanostructured steel is attributed to the higher protectiveness of the Cr-rich spinel layer and the less defective Ni-rich layer beneath it. Recrystallization occurred exclusively in the Ni-rich region, while the deformed steel underwent recovery during exposure. The thickness of the recrystallization layer was 2.9 mu m at 759 h, increased to 8 mu m at 1638 h, and remained stable thereafter. The size of recrystallized grains in SP-samples processed under pressure of 0.06 MPa and 0.15 MPa was approximately 2.92 mu m, whereas it was about 1.32 mu m for 0.25 MPa processed sample.
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页数:14
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