Fabrication of highly ordered porous nickel oxide anode materials and their electrochemical characteristics in lithium storage

被引：0
|
作者：
机构：
[1] [1,Miao, Fengjuan
[2] Li, Qianqian
[3] 2,Tao, Bairui
[4] Chu, Paul K.
来源：
Tao, B. (tbr_sir@163.com) | 1600年 / Elsevier Ltd卷 / 594期
关键词：
The structure and electrochemical properties of silicon microchannel plates (MCP)-supported NiO nanocomposites (NiO/Si-MCP) synthesized by silicon micromachining; electroless plating; and thermal annealing are investigated as anodes in lithium ion batteries. Galvanostatic charge and discharge results indicate that the NiO/Si-MCP is capable of delivering a higher capacity than the bare nickel-oxide film. At a 1 C current; the NiO/Si-MCP nanocomposite film shows an enormous first discharge capacity of about 3190 mA g-1 and charge capacity of 1977 mA g-1. After 15 cycles; the NiO/Si-MCP nanocomposite retains a reversible capacity of 1531 mA g-1 with 63.7% of the capacity maintained in the 2nd cycle. The lithium storage capacity is maintained at ∼880 mA h g-1 after 50 discharge/charge cycles and it is much larger than that of NiO and its composites. The enhanced electrochemical performance of the highly ordered three-dimensional materials is attributed to the synergistic effects offered by the silicon microchannel plates in the nickel oxide film subsequently facilitating electrolyte penetration; diffusion; and migration. The structure is promising anode materials in lithium-ion batteries. © 2014 Elsevier B.V. All rights reserved;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
相关论文
共 50 条
  • [41] Facile fabrication of CuO nanosheets on Cu substrate as anode materials for electrochemical energy storage
    Liu, Yang
    Qiao, Yun
    Zhang, Wuxing
    Hu, Pei
    Chen, Chaoji
    Li, Zhen
    Yuan, Lixia
    Hu, Xianluo
    Huang, Yunhui
    JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 586 : 208 - 215
  • [42] Fabrication and field emission characteristics of highly ordered titanium oxide nanodot arrays
    Chen, PL
    Huang, WJ
    Chang, JK
    Kuo, CT
    Pan, FM
    ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (10) : H83 - H86
  • [43] Characteristics of Anode Materials for Nickel Electroforming
    Green, T. A.
    Tambe, C. Enowmbi
    Roy, S.
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2022, 169 (09)
  • [44] Electrochemical presodiation promoting lithium storage performance of Mo-based anode materials
    Li, Huiyong
    Liu, Ping
    Zhou, Nan
    Huang, Xiaobing
    Wang, Haiyan
    CERAMICS INTERNATIONAL, 2017, 43 (15) : 11967 - 11972
  • [45] Synthesis of porous Mn2O3 embedded in reduced graphene oxide as advanced anode materials for lithium storage
    Zhang, Lingling
    Ge, Danhua
    Geng, Hongbo
    Zheng, Junwei
    Cao, Xueqin
    Gu, Hongwei
    NEW JOURNAL OF CHEMISTRY, 2017, 41 (15) : 7102 - 7107
  • [46] Fabrication of highly porous mullite materials
    Barea, R
    Osendi, MI
    Miranzo, P
    Ferreira, JMF
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (03) : 777 - 779
  • [47] Ti-Based Oxide Anode Materials for Advanced Electrochemical Energy Storage: Lithium/Sodium Ion Batteries and Hybrid Pseudocapacitors
    Lou, Shuaifeng
    Zhao, Yang
    Wang, Jiajun
    Yin, Geping
    Du, Chunyu
    Sun, Xueliang
    SMALL, 2019, 15 (52)
  • [48] Highly ordered nanoporous Sn-Ni alloy film anode with excellent lithium storage performance
    Wan, Hui
    Chen, Zhewei
    Yuan, Mengqi
    Wang, Jianming
    Zhang, Jianqing
    MATERIALS LETTERS, 2015, 138 : 139 - 142
  • [49] Porous nickel oxide/nickel films for electrochemical capacitors
    Liu, KC
    Anderson, MA
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) : 124 - 130
  • [50] Fabrication of porous carbon nanofibers and their application as anode materials for rechargeable lithium-ion batteries
    Ji, Liwen
    Zhang, Xiangwu
    NANOTECHNOLOGY, 2009, 20 (15)
12345