Effect of morphology on the electric conductivity of binary polymer blends filled with carbon black

被引:0
|
作者
Institute of Polymer Composites, Zhejiang University, Hangzhou, Zhejiang 310027, China [1 ]
不详 [2 ]
机构
来源
Journal of Applied Polymer Science | 2007年 / 106卷 / 03期
关键词
Several carbon black (CB)-filled binary polymer blends were prepared in Haake rheometer. Distribution states of CB and effect of morphology on the electric conductivity of different ternary composites were investigated. Under our experimental condition CB particles located preferentially at the interface between polymethyl methacrylate (PMMA) and polypropylene (PP) in PMMA/PP/CB composites; in high-density polyethylene (HDPE) phase in PP/HDPE/CB composites; and in Nylon6 (PA6) phase in polystyrene (PS)/PA6/CB; PP/PA6/CB; PMMA/PA6/CB; and polyacrylonitrile (PAN)/PA6/CB composites; the ternary composites in which CB particles locate at the interface of two polymer components have the highest electric conductivity when the mass ratio of the two polymers is near to 1 : 1. The ternary composites in which CB particles located preferentially in one polymer have the highest electric conductivity usually when the amount of the polymer component having CB particles is comparatively less than the amount of the polymer component not having CB particles; if the formulations of PS/PA6/CB; and PMMA/PA6/CB composites equaled and PA6/CB in them is in dispersed phase; PS/PA6/CB composites have the highest electric conductivity and PP/PA6/CB composites have the lowest electric conductivity; suitable amount of PS or PAN in PA6/CB composites increase the electric conductivity due in the formation of a parallel electrocircuit for electrons to transmit. © 2007 Wiley Periodicals; Inc;
D O I
暂无
中图分类号
学科分类号
摘要
Journal article (JA)
引用
收藏
页码:2008 / 2017
相关论文
共 50 条
  • [41] Carbon black-filled PET/HDPE blends: Effect of the CB structure on rheological and electric properties
    Mallette, JG
    Quej, LM
    Marquez, A
    Manero, O
    JOURNAL OF APPLIED POLYMER SCIENCE, 2001, 81 (03) : 562 - 569
  • [42] Effect of carbon-black treatment by radiation emulsion polymerization on temperature dependence of resistivity of carbon-black-filled polymer blends
    Jia, SJ
    Jiang, PK
    Zhang, ZC
    Wang, ZG
    RADIATION PHYSICS AND CHEMISTRY, 2006, 75 (04) : 524 - 531
  • [43] Carbon black effect on the microstructure of incompatible polymer blends
    del Río, C
    Ojeda, MC
    Acosta, JL
    EUROPEAN POLYMER JOURNAL, 2000, 36 (08) : 1687 - 1695
  • [44] Carbon black-filled polymer blends: A scanning probe microscopy characterization
    Leclere, P
    Lazzaroni, R
    Gubbels, F
    Calberg, C
    Dubois, P
    Jerome, R
    Bredas, JL
    NANOPHASE AND NANOCOMPOSITE MATERIALS II, 1997, 457 : 475 - 480
  • [45] Conductive polymer blends filled with carbon black: Positive temperature coefficient behavior
    Materials Science Institute, Zhongshan University, Guangzhou 510275, China
    不详
    Polym Eng Sci, 9 (1678-1688):
  • [46] Improvement of conductive network quality in carbon black-filled polymer blends
    Hou, Yan Hui
    Zhang, Ming Qiu
    Rong, Min Zhi
    Yu, Gang
    Zeng, Han Min
    1600, John Wiley and Sons Inc. (84):
  • [47] Improvement of conductive network quality in carbon black-filled polymer blends
    Hou, YH
    Zhang, MQ
    Rong, MZ
    Yu, G
    Zeng, HM
    JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 84 (14) : 2768 - 2775
  • [48] Conductive polymer blends filled with carbon black: Positive temperature coefficient behavior
    Yu, G
    Zhang, Q
    Zeng, HM
    Hou, YH
    Zhang, HB
    POLYMER ENGINEERING AND SCIENCE, 1999, 39 (09): : 1678 - 1688
  • [49] Enhancing the conductivity of carbon nanotube filled blends by tuning their phase separated morphology with a copolymer
    Bharati, Avanish
    Cardinaels, Ruth
    Seo, Jin Won
    Wubbenhorst, Michael
    Moldenaers, Paula
    POLYMER, 2015, 79 : 271 - 282
  • [50] Morphology and electric conductivity of cross-linked polyethylene–carbon black blends prepared by gelation/ crystallization from solutions
    C. Xu
    Y. Bin
    Y. Agari
    M. Matsuo
    Colloid and Polymer Science, 1998, 276 : 669 - 679