SBR/clay nanocomposites with enhanced mechanical and gas barrier properties

被引:0
|
作者
Meneghetti, P. [1 ]
Shaikh, S. [1 ]
Qutubuddin, S. [1 ]
Nazarenko, S. [2 ]
机构
[1] Department of Chemical Engineering, Case Western Reserve University, Cleveland, OH, United States
[2] Department of Polymer Science and Engineering, School of Polymers and High Performance Materials, University of Southern Mississippi, Hattiesburg, MS, United States
来源
Gummi, Fasern, Kunststoffe | 2010年 / 63卷 / 07期
关键词
X ray diffraction - Dispersions - Aspect ratio - High resolution transmission electron microscopy;
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中图分类号
学科分类号
摘要
The surfactant chain length and functional groups affected the dispersion of clay nanolayers in the matrix and the overall properties of the nanocomposites. X-ray diffraction (XRD) revealed peaks corresponding to intercalated structures; transmission electron microscopy (TEM) observations agreed well with XRD assessment of the composites. SBR/VODAC-MMT system exhibited the best dispersion among the nanocomposites studied. VODAC-MMT was partially exfoliated in SBR matrix and the average aspect ratio of the nanolayer stacks or aggregates was high [20]. Depending on the amount of clay, considerable mechanical reinforcement and gas barrier enhancement were achieved in nanocomposites over pure rubber.
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页码:405 / 416
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