Mo2C catalyst leads to highly efficient hydrogen transfer of alcohols and amines to synthesize N-alkylamines

被引：0

作者：

Chen, Yimei ^{[1
]}

Wang, Zhe ^{[1
]}

Long, Zhouyang ^{[2
]}

Wang, Yunfei ^{[1
]}

Zhang, Pingbo ^{[1
]}

Leng, Yan ^{[1
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Key Lab Synthet & Biol Colloids, Minist Educ, Wuxi 214122, Jiangsu, Peoples R China

[2] Jiangsu Normal Univ, Sch Chem & Mat Sci, Jiangsu Key Lab Green Synthet Chem Funct Mat, Xuzhou 221116, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 93期

基金：

中国国家自然科学基金;

关键词：

HYDRODEOXYGENATION; NANOPARTICLES;

D O I：

10.1039/d4cc04327h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We found that molybdenum carbide (Mo2C) can be applied as a novel and efficient heterogeneous catalyst for hydrogen transfer of anilines and alcohols to synthesize N-alkylamines. The results of experiments and DFT calculations demonstrate that Mo2C surface can reduce the energy barrier of the key step of alcohol dehydrogenation and generate a hydrogen spillover effect, thereby exhibiting outstanding catalytic performance.

引用

页码：13750 / 13753

页数：4

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