Mo2C catalyst leads to highly efficient hydrogen transfer of alcohols and amines to synthesize N-alkylamines

被引：0

作者：

Chen, Yimei ^{[1
]}

Wang, Zhe ^{[1
]}

Long, Zhouyang ^{[2
]}

Wang, Yunfei ^{[1
]}

Zhang, Pingbo ^{[1
]}

Leng, Yan ^{[1
]}

机构：

[1] Jiangnan Univ, Sch Chem & Mat Engn, Key Lab Synthet & Biol Colloids, Minist Educ, Wuxi 214122, Jiangsu, Peoples R China

[2] Jiangsu Normal Univ, Sch Chem & Mat Sci, Jiangsu Key Lab Green Synthet Chem Funct Mat, Xuzhou 221116, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 93期

基金：

中国国家自然科学基金;

关键词：

HYDRODEOXYGENATION; NANOPARTICLES;

D O I：

10.1039/d4cc04327h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We found that molybdenum carbide (Mo2C) can be applied as a novel and efficient heterogeneous catalyst for hydrogen transfer of anilines and alcohols to synthesize N-alkylamines. The results of experiments and DFT calculations demonstrate that Mo2C surface can reduce the energy barrier of the key step of alcohol dehydrogenation and generate a hydrogen spillover effect, thereby exhibiting outstanding catalytic performance.

引用

页码：13750 / 13753

页数：4

共 50 条

[1] β-Mo2C/N, P-co-doped carbon as highly efficient catalyst for hydrogen evolution reaction
Tan, Jiabin
He, Xiaobo
Yin, Fengxiang
Liang, Xin
Chen, Biaohua
Li, Guoru
Yin, Huaqiang
JOURNAL OF MATERIALS SCIENCE, 2019, 54 (06) : 4589 - 4600
[2] β-Mo2C/N, P-co-doped carbon as highly efficient catalyst for hydrogen evolution reaction
Jiabin Tan
Xiaobo He
Fengxiang Yin
Xin Liang
Biaohua Chen
Guoru Li
Huaqiang Yin
Journal of Materials Science, 2019, 54 : 4589 - 4600
[3] Porous Mo2C nanorods as an efficient catalyst for the hydrogen evolution reaction
Zhao, Yufei
Wang, Shijian
Liu, Hao
Guo, Xin
Zeng, Xingrong
Wu, Wenjian
Zhang, Jinqiang
Wang, Guoxiu
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2019, 132 : 230 - 235
[4] Efficient and Stable Co/β-Mo2C Catalyst for Hydroformylation
Wei, Baiyin
Liu, Xiaofang
Deng, Yuchao
Hua, Kaimin
Chen, Junjun
Wang, Hui
Sun, Yuhan
ACS CATALYSIS, 2021, 11 (23) : 14319 - 14327
[5] Hierarchical Mo2C/C Scaffolds Organized by Nanosheets as Highly Efficient Electrocatalysts for Hydrogen Production
Wang, Dezhi
Guo, Ting
Wu, Zhuangzhi
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2018, 6 (11): : 13995 - 14003
[6] N-doped Mo2C nanoblock for efficient hydrogen evolution reaction
Yang Li
Qilin Huang
Hongbiao Wu
Lun Cai
Yiming Du
Shiqiu Liu
Zongqiang Sheng
Mingzai Wu
Journal of Solid State Electrochemistry, 2019, 23 : 2043 - 2050
[7] N-doped Mo2C nanoblock for efficient hydrogen evolution reaction
Li, Yang
Huang, Qilin
Wu, Hongbiao
Cai, Lun
Du, Yiming
Liu, Shiqiu
Sheng, Zongqiang
Wu, Mingzai
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2019, 23 (07) : 2043 - 2050
[8] Highly efficient electrocatalytic hydrogen evolution promoted by O-Mo-C interfaces of ultrafine β-Mo2C nanostructures
Yang, Hui
Chen, Xing
Hu, Guoxiang
Chen, Wan-Ting
Bradley, Siobhan J.
Zhang, Weijie
Verma, Gaurav
Nann, Thomas
Jiang, De-en
Kruger, Paul E.
Wang, Xiangke
Tian, He
Waterhouse, Geoffrey I. N.
Telfer, Shane G.
Ma, Shengqian
CHEMICAL SCIENCE, 2020, 11 (13) : 3523 - 3530
[9] Electrochemical performance of α-Mo2C as catalyst for the hydrogen evolution reaction
Garcia, G.
Roca-Ayats, M.
Guillen-Villafuerte, O.
Rodriguez, J. L.
Arevalo, M. C.
Pastor, E.
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2017, 793 : 235 - 241
[10] Mo2C/C catalyst as efficient peroxymonosulfate activator for carbamazepine degradation
Bao, Yujie
Chen, Ting
Zhu, Zhiliang
Zhang, Hua
Qiu, Yanling
Yin, Daqiang
CHEMOSPHERE, 2022, 287

← 1 2 3 4 5 →