Synthesis of H-shaped chromophores with diallyl groups

被引：0
|
作者：
Fang, M. [1 ]
Pan, C. [1 ]
Lin, Z. [1 ]
Lu, G.-Y. [2 ]
机构：
[1] College of Chemical Engineering, Nanjing Forestry University, Nanjing,210037, China
[2] Department of Chemistry, Nanjing University, Nanjing,210093, China
来源：
Materials Research Innovations | 2015年 / 19卷
关键词：
Optical materials;
D O I：
10.1179/1432891715Z.0000000001794
中图分类号：
学科分类号：
摘要：
Two novel H-shaped chromophores with diallyl groups using 9,10-dihydroanthracene as molecular backbone were synthesised by a six-step reaction including Claisen rearrangement, Rieche formylation reaction and Knoevenagel condensation. Crystal structures of two intermediates 4 and 6 were measured, which demonstrate that the two D-?-A units in a single chromophore molecule are closely arranged in the same direction. Therefore, they will exhibit much higher first molecular hyperpolarisability, which will be used in the preparation of polymeric non-linear optical materials. © W. S. Maney & Son Ltd 2015.
引用
收藏
页码：754 / 757
相关论文
共 50 条
  • [31] Designing H-shaped micromechanical filters
    Arhaug, O. P.
    Soeraasen, O.
    INTERNATIONAL MEMS CONFERENCE 2006, 2006, 34 : 686 - 691
  • [32] Fractal H-shaped plasmonic nanocavity
    Li, Guanhai
    Chen, Xiaoshuang
    Ni, Bo
    Li, Oupeng
    Huang, Lujun
    Jiang, Yuan
    Hu, Weida
    Lu, Wei
    NANOTECHNOLOGY, 2013, 24 (20)
  • [33] PREPARATION AND CHARACTERIZATION OF H-SHAPED POLYSTYRENES
    ROOVERS, J
    TOPOROWSKI, PM
    MACROMOLECULES, 1981, 14 (05) : 1174 - 1178
  • [34] Synthesis and mesomorphic properties of new azo H-shaped liquid crystal compounds
    He, Qing-Qing
    Zhang, Zi-Yun
    Li, Chun-Yang
    Liu, Ya-Ping
    Hu, Ji-Wen
    Wang, Xin-Jiao
    Jia, Ying-Gang
    Tian, Mei
    Yao, Dan-Shu
    LIQUID CRYSTALS, 2021, 48 (14) : 1992 - 2001
  • [35] Design and synthesis of novel H-Shaped chromophore for enhanced nonlinear optical properties
    Xu, Huajun
    Liu, Fenggang
    Chen, Shujie
    Shi, Wenjing
    Xie, Zhipeng
    Wang, Jianwu
    Zhai, Zhaofen
    Liu, Jianpeng
    Li, Han
    Wang, Jiahai
    DYES AND PIGMENTS, 2019, 165 : 144 - 150
  • [36] ROMPing in and out: Synthesis and self-assembly of conjugated H-shaped polymers
    Kalow, Julia
    Swager, Timothy
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
  • [37] Synthesis and Dilute Solution Properties of Well-Defined H-Shaped Polybutadienes
    Rahman, M. Shahinur
    Aggarwal, Ravi
    Larson, Ronald G.
    Dealy, John M.
    Mays, Jimmy
    MACROMOLECULES, 2008, 41 (21) : 8225 - 8230
  • [38] Analyses of compact H-shaped microstrep antenna
    Ansari, J. A.
    Dubey, Satya Kesh
    Singh, Prabhakar
    Khan, R. U.
    Vishvakarma, Babau R.
    MICROWAVE AND OPTICAL TECHNOLOGY LETTERS, 2008, 50 (07) : 1779 - 1784
  • [39] Small H-shaped antennas for MMIC applications
    Singh, D
    Kalialakis, C
    Gardner, P
    Hall, PS
    IEEE TRANSACTIONS ON ANTENNAS AND PROPAGATION, 2000, 48 (07) : 1134 - 1141
  • [40] Stacked H-shaped microstrip patch antenna
    Anguera, J
    Boada, L
    Puente, C
    Borja, C
    Soler, J
    IEEE TRANSACTIONS ON ANTENNAS AND PROPAGATION, 2004, 52 (04) : 983 - 993
12345