Ultra-trace speciation analysis of thallium in environmental water samples by inductively coupled plasma mass spectrometry after a novel sequential mixed-micelle cloud point extraction

被引：0
|
作者：
Meeravali, Noorbasha N. [1 ]
Jiang, Shiuh-Jen [2 ]
机构：
[1] National Center for Compositional Characterization of Materials (CCCM), Hyderabad, India
[2] Department of Chemistry, National Sun Yat-sen University, Kaohsiung 80424, Taiwan
来源：
Journal of Analytical Atomic Spectrometry | 2008年 / 23卷 / 04期
关键词：
A simple and novel sequential mixed-micelle cloud point extraction procedure has been developed for ultra-trace speciation analysis of thallium in environmental water samples by inductively coupled plasma mass spectrometry (ICP-MS). A mixed micelle consisting of sodium dodecyl sulfate (SDS) and Triton X-114 is used as a chelating as well as an extracting agent. Tl(iii)-DTPA (diethylenetriaminepentaacetic acid) complex in an HCl medium is extracted into a surfactant-rich phase in the presence of Tl(i). The Tl(i) in the supernatant is subjected to a similar extraction procedure after bromine oxidation. Ultrasonically assisted back-extraction is used to extract the Tl(iii) species from the surfactant-rich phase into a small volume of aqueous l-cysteine. The pre-concentration factor and detection limit are 125 and 0.02 pg mL -1; respectively. The recoveries are in the range 98-103% at 10-20 pg mL-1 Tl(iii) with relative standard deviation (RSD) of 1-3%. The procedure is validated by comparing the sum of the concentrations of individual Tl species with total thallium concentration in certified reference materials such as Trace elements in water NIST SRM 1643c and Open ocean seawater NASS-4 and NASS-5; and also by applying it to various samples collected locally. © The Royal Society of Chemistry 2008;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
页码：555 / 560
相关论文
共 50 条
  • [21] Determination of heavy metals in water samples using dual-cloud point extraction coupled with inductively coupled plasma mass spectrometry
    Peng, Guilong
    He, Qiang
    Zhou, Guangming
    Li, Yong
    Su, Xiaoxuan
    Liu, Mengzi
    Fan, Leilei
    ANALYTICAL METHODS, 2015, 7 (16) : 6732 - 6739
  • [22] Speciation of cisplatin in environmental water samples by hydrophilic interaction liquid chromatography coupled to inductively coupled plasma mass spectrometry
    Vidmar, Janja
    Martincic, Anze
    Milacic, Radmila
    Scancar, Janez
    TALANTA, 2015, 138 : 1 - 7
  • [23] Interference free ultra trace determination of Pt, Pd and Au in geological and environmental samples by inductively coupled plasma quadrupole mass spectrometry after a cloud point extraction (vol 23, pg 854, 2008)
    Meeravali, Noorbasha N.
    Jiang, Shiuh-Jen
    JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2008, 23 (12) : 1693 - 1693
  • [24] DETERMINATION OF BISMUTH AT ULTRA-TRACE LEVELS IN SEA-WATER BY INDUCTIVELY COUPLED PLASMA MASS-SPECTROMETRY AFTER PRECONCENTRATION WITH SOLVENT-EXTRACTION AND BACK-EXTRACTION
    SHABANI, MB
    SAHOO, SK
    MASUDA, A
    ANALYST, 1992, 117 (09) : 1477 - 1480
  • [25] Determination of ultra-trace levels of cobalt in water and wheat flour samples using cloud point extraction coupled with laser thermal lens spectrometry
    Han, Quan
    Huo, Yanyan
    Yang, Xiaohui
    He, Yaping
    Wu, Jiangyan
    Cai, Hongli
    ANALYTICAL METHODS, 2018, 10 (06) : 634 - 640
  • [26] Determination of ultra-trace levels of palladium in water samples by cloud point extraction and graphite furnace atomic absorption spectrometry
    Han, Quan
    Huo, Yanyan
    Yang, Xiaohui
    Yao, Xing
    JOURNAL OF CHEMICAL RESEARCH, 2021, 45 (9-10) : 883 - 889
  • [27] Determination of ultra-trace rare earth elements in ultramafic and sulfide samples by quadrupole inductively coupled plasma-mass spectrometry
    Sun, Yali
    Sun, Min
    JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2009, 24 (02) : 232 - 236
  • [28] Separation and preconcentration of ultra trace amounts of beryllium in water samples using mixed micelle-mediated extraction and determination by inductively coupled plasma-atomic emission spectrometry
    Beiraghi, Assadollah
    Babaee, Saeed
    ANALYTICA CHIMICA ACTA, 2008, 607 (02) : 183 - 190
  • [29] Analysis of Ultra-Trace Impurities in High Purity Molybdenum Powder through Inductively Coupled Plasma Tandem Mass Spectrometry
    Fu Liang
    Shi Shu-yun
    Tang You-gen
    Wang Hai-yan
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38 (08) : 2588 - 2594
  • [30] Arsenic speciation in water and biota samples at trace levels by ion chromatography inductively coupled plasma-mass spectrometry
    Firat, Merve
    Bakirdere, Sezgin
    Sel, Sabriye
    Chormey, Dotse Selali
    Elkiran, Omer
    Erulas, Fatih
    Turak, Fatma
    INTERNATIONAL JOURNAL OF ENVIRONMENTAL ANALYTICAL CHEMISTRY, 2017, 97 (07) : 684 - 693
12345