High fidelity self-sorting assembling of meso-cinchomeronimide appended meso-meso linked Zn(II) diporphyrins

被引：0

作者：

Kamada, Taisuke ^{[1
]}

Aratani, Naoki ^{[1
]}

Ikeda, Toshiaki ^{[1
]}

Shibata, Naoki ^{[2
,3
]}

Higuchi, Yoshiki ^{[2
,3
]}

Wakamiya, Atsushi ^{[4
]}

Yamaguchi, Shigehiro ^{[4
]}

Kim, Kil Suk ^{[5
]}

Yoon, Zin Seok ^{[5
]}

Kim, Dongho ^{[5
]}

Osuka, Atsuhiro ^{[1
]}

机构：

[1] Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan

[2] Graduate School of Life Science, University of Hyogo, 3-2-1 Koto, Kamigori-cho, Ako-gun, Hyogo 678-1297, Japan

[3] RIKEN Harima Institute/SPring-8, 1-1-1 Koto, Mikazuki-cho, Sayo-gun, Hyogo 679-5248, Japan

[4] Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan

[5] Center for Ultrafast Optical Characteristics Control, Department of Chemistry, Yonsei University, Seoul 120-749, Korea, Republic of

来源：

Journal of the American Chemical Society | 2006年 / 128卷 / 23期

关键词：

In noncoordinating solvents; meso-cinchomeronimide appended Zn(II) porphyrin 2 forms a cyclic trimer; while diporphyrins 7 exhibit high-fidelity self-sorting assembling to form discrete cyclic trimer; tetramer; and pentamer with large association constants from 7in-in; 7in-out; and; 7out-out; respectively; through almost perfect discrimination of enantiomeric and conformational differences of the mesocinchomeronimide substituents. In the latter self-sorting processes; the dihedral angles dictated by the two pyridyl nitrogen atoms control the size of the aggregates; the trimer from 7in-in; the tetarmer from 7in-out; and the pentamer from 7out-out. Cyclic structures of (2)3 and (R-7out-out)5 have been determined by single-crystal X-ray diffraction analysis. © 2006 American Chemical Society;

D O I：

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中图分类号：

学科分类号：

摘要：

Journal article (JA)

引用

页码：7670 / 7678

共 25 条

[21] A self-assembled porphyrin box from meso-meso-linked bis{5-p-pyridyl-15-(3,5-di-octyl-oxyphenyl)porphyrinato zinc(II)}
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Sakamoto, S
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[22] Self-assembling covalently linked supramolecular arrays of defined structure: The remarkable redox reactivity of 15-meso-substituted 5-oxyporphyrins
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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (21): : 2496 - 2499
[23] Self-assembling covalently linked supramolecular arrays of defined structure: The remarkable redox reactivity of 15-meso-substituted 5-oxyporphyrins
Department of Chemistry, University of California, Davis, CA 95616-5295, United States
不详
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Angew Chem (Int Ed Engl), 21 (2496-2499):
[24] Molecular-Shape-Dependent Photophysical Properties of meso-β Doubly Linked Zn(II) Porphyrin Arrays and Their Indene-Fused Analogues
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[25] Efficient Forster Resonance Energy Transfer in 1,2,3-Triazole Linked BODIPY-Zn(II) Meso-tetraphenylporphyrin Donor-Acceptor Arrays
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