High fidelity self-sorting assembling of meso-cinchomeronimide appended meso-meso linked Zn(II) diporphyrins

被引：0

作者：

Kamada, Taisuke ^{[1
]}

Aratani, Naoki ^{[1
]}

Ikeda, Toshiaki ^{[1
]}

Shibata, Naoki ^{[2
,3
]}

Higuchi, Yoshiki ^{[2
,3
]}

Wakamiya, Atsushi ^{[4
]}

Yamaguchi, Shigehiro ^{[4
]}

Kim, Kil Suk ^{[5
]}

Yoon, Zin Seok ^{[5
]}

Kim, Dongho ^{[5
]}

Osuka, Atsuhiro ^{[1
]}

机构：

[1] Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan

[2] Graduate School of Life Science, University of Hyogo, 3-2-1 Koto, Kamigori-cho, Ako-gun, Hyogo 678-1297, Japan

[3] RIKEN Harima Institute/SPring-8, 1-1-1 Koto, Mikazuki-cho, Sayo-gun, Hyogo 679-5248, Japan

[4] Department of Chemistry, Graduate School of Science, Nagoya University, Chikusa, Nagoya 464-8602, Japan

[5] Center for Ultrafast Optical Characteristics Control, Department of Chemistry, Yonsei University, Seoul 120-749, Korea, Republic of

来源：

Journal of the American Chemical Society | 2006年 / 128卷 / 23期

关键词：

In noncoordinating solvents; meso-cinchomeronimide appended Zn(II) porphyrin 2 forms a cyclic trimer; while diporphyrins 7 exhibit high-fidelity self-sorting assembling to form discrete cyclic trimer; tetramer; and pentamer with large association constants from 7in-in; 7in-out; and; 7out-out; respectively; through almost perfect discrimination of enantiomeric and conformational differences of the mesocinchomeronimide substituents. In the latter self-sorting processes; the dihedral angles dictated by the two pyridyl nitrogen atoms control the size of the aggregates; the trimer from 7in-in; the tetarmer from 7in-out; and the pentamer from 7out-out. Cyclic structures of (2)3 and (R-7out-out)5 have been determined by single-crystal X-ray diffraction analysis. © 2006 American Chemical Society;

D O I：

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中图分类号：

学科分类号：

摘要：

Journal article (JA)

引用

页码：7670 / 7678

共 25 条

[1] High fidelity self-sorting assembling of meso-cinchomeronimide appended meso-meso linked Zn(II) diporphyrins
Kamada, Taisuke
Aratani, Naoki
Ikeda, Toshiaki
Shibata, Naoki
Higuchi, Yoshiki
Wakamiya, Atsushi
Yamaguchi, Shigehiro
Kim, Kil Suk
Yoon, Zin Seok
Kim, Dongho
Osuka, Atsuhiro
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (23) : 7670 - 7678
[2] meso-alkyl-substituted meso-meso linked diporphyrins and meso-alkyl-substituted meso-meso, β-β, β-β triply linked diporphyrins
Hiroto, S
Osuka, A
JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (10): : 4054 - 4058
[3] Chiral self-discriminative self-assembling of meso-meso linked diporphyrins
Maeda, Chihiro
Kamada, Taisuke
Aratani, Naoki
Osuka, Atsuhiro
COORDINATION CHEMISTRY REVIEWS, 2007, 251 (21-24) : 2743 - 2752
[4] Meso-meso linked diporphyrins from 5,10,15-trisubstituted porphyrins
Yoshida, N
Shimidzu, K
Osuka, A
CHEMISTRY LETTERS, 1998, (01) : 55 - 56
[5] Regioselective [3+4] cycloaddition of an azomethine ylide to meso-meso, β-β, β′-β′ triply linked diporphyrins
Tanaka, Takayuki
Nakamura, Yasuyuki
Aratani, Naoki
Osuka, Atsuhiro
TETRAHEDRON LETTERS, 2008, 49 (20) : 3308 - 3311
[6] Control of dihedral angle of meso-meso linked diporphyrins by introducing dioxymethylene straps of various length
Yoshida, N
Osuka, A
ORGANIC LETTERS, 2000, 2 (19) : 2963 - 2966
[7] meso,meso′-Bis(5-azaindol-2-yl)-Appended meso-meso-Linked Zn(II) Diporphyrin: A Discrete Fluorescent Assembly
Maeda, Chihiro
Shinokubo, Hiroshi
Osuka, Atsuhiro
ORGANIC LETTERS, 2009, 11 (22) : 5322 - 5325
[8] Effect of conformational heterogeneity on excitation energy transfer efficiency in directly meso-meso linked Zn(II) porphyrin arrays
Ahn, TK
Yoon, ZS
Hwang, IW
Lim, JK
Rhee, H
Joo, T
Sim, E
Kim, SK
Aratani, N
Osuka, A
Kim, D
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (22): : 11223 - 11230
[9] Excitonic coupling strength and coherence length in the singlet and triplet excited states of meso-meso directly linked Zn(II)porphyrin arrays
Ha, JH
Cho, HS
Song, JK
Kim, D
Aratani, N
Osuka, A
CHEMPHYSCHEM, 2004, 5 (01) : 57 - 67
[10] Excitation energy transfer rate constants in meso-meso linked Zn(II) porphyrin arrays with energy accepting 5,15-bisphenylethynylated Zn(II) porphyrin
Ko, D
Kim, H
Park, JH
Kim, D
Sim, E
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2005, 26 (10): : 1505 - 1511

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