Optical properties of vanadium dioxide film during semiconductive-metallic phase transition

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Kakiuchida, Hiroshi [1 ]
Jin, Ping [1 ]
Nakao, Setsuo [1 ]
Tazawa, Masato [1 ]
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[1] Materials Research Institute for Sustainable Development, National Institute of Advanced Industrial Science and Technology (AIST), 2266-98 Anagahora, Moriyama, Nagoya 463-8560, Japan
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The optical constants of vanadium dioxide (VO2) films were determined at visible and near-infrared wavelengths at various temperatures during a semiconductive-metallic phase transition by ellipsometric analysis with Lorentz-oscillator formulae. The reversible changes in optical constants against temperature due to thermochromism were observed at around 70°C. The wavelength dispersions of the optical constants were well expressed by the sum of three oscillators and their oscillating energies were attributed to photon-excited transitions. The variation in band structure during the phase transition was monitored; and the relationship between the band structure and optical properties was discussed. © 2007 The Japan Society of Applied Physics;
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