Photochemical Deracemization of Lactams with Deuteration Enabled by Dual Hydrogen Atom Transfer

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作者
Yan, Xiaoyu [1 ]
Pang, Yubing [1 ]
Zhou, Yutong [1 ]
Chang, Rui [1 ]
Ye, Juntao [1 ]
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[1] Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs, Frontiers Science Center for Transformative Molecules, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai,200240, China
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Financial support from the National Natural Science Foundation of China (grant no. 22371180) and Shanghai Jiao Tong University are acknowledged. We thank Prof. Todd Hyster (Princeton University); Prof. Manuel Plaza (University of Oviedo); and Prof. Xiao-Song Xue (Shanghai Institute of Organic Chemistry) for helpful discussions. Dr. Pandaram Sakthivel and Dr. Hasil Aman of our group are acknowledged for reproducing the results of compound d - 1q; d; -; 1u; 2h; and d - 2l . 1 1 1 1;
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