Graphitic carbon nitride-PTD hybrid catalyst for efficient photocatalytic oxidative coupling of arylamine for the production of azoaromatic under visible light

被引:0
|
作者
Singh, Nidhi [1 ]
Yadav, Rajesh K. [1 ]
Mishra, Shaifali [1 ]
Shahin, Rehana [1 ]
Singh, Satyam [1 ]
Singhal, Rajat [2 ]
Gupta, Navneet K. [2 ]
Baeg, Jin-OoK [3 ]
Obaidullah, Ahmad J. [4 ]
Yadav, Krishna Kumar [5 ,6 ]
Umar, Ahmad [7 ,8 ,9 ]
Almas, Tubia [7 ,8 ]
机构
[1] Madan Mohan Malaviya Univ Technol, Dept Chem & Environm Sci, Gorakhpur 273010, Uttar Pradesh, India
[2] Indian Inst Sci, Ctr Sustainable Technol, Bangalore Gulmohar Marg, Bengaluru 560012, India
[3] Korea Res Inst Chem Technol, 141 Gajeong Ro, Daejeon, South Korea
[4] King Saud Univ, Coll Pharm, Dept Pharmaceut Chem, POB 2457, Riyadh 11451, Saudi Arabia
[5] Madhyanchal Profess Univ, Fac Sci & Technol, Bhopal 462044, India
[6] Al Ayen Univ, Sci Res Ctr, Environm & Atmospher Sci Res Grp, Nasiriyah 64001, Iraq
[7] Najran Univ, Fac Sci & Arts, Dept Chem, Najran 11001, Saudi Arabia
[8] Najran Univ, PCSED, Najran 11001, Saudi Arabia
[9] Ohio State Univ, Dept Mat Sci & Engn, Columbus, OH 43210 USA
关键词
G-PTD photocatalyst; Graphitic carbon nitride; Azo; -N=N- group; Dyes; SOLAR FUEL PRODUCTION; HIGHLY EFFICIENT; H-2; EVOLUTION; NANOPARTICLES; SYSTEM;
D O I
10.1016/j.molstruc.2024.139144
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Oxidative coupling of amine derivatives to selectively synthesize pharmaceutical materials has been realized via photocatalysis. Herein we report on the fabrication and development of a graphitic carbon nitride (G) based visible light active photocatalyst (G-PTD), which is melamine converted graphitic carbon nitride(G) covalently integrated to a light harvesting perylene tetracarboxylic dianhydride (PTD) molecule. The synthesized photocatalyst has various functions in a highly active manner leading to high yield of newly generated azoaromatic compound. The current research endeavour highlights on the fabrication and utilization of a graphitic carbon nitride based photocatalyst for direct oxidative coupling of arylamines.
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页数:8
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