Preparation and Property of Superhydrophobic and Photocatalytic Polydimethylsilane/Nano-TiO2 Self-Cleaning Coating

被引:0
|
作者
Liu R. [1 ,2 ]
Ding X. [2 ]
Zhao J. [2 ]
Hu J. [2 ]
Mu J. [2 ]
Fu X. [2 ]
机构
[1] College of Materials and Environmental Engineering, Fujian Polytechnic Normal University, Fuqing
[2] College of Ecological and Resources Engineering, Wuyi University, Wuyishan
关键词
Composite coating; Photocatalysis; Self-cleaning; Superhydrophobicity;
D O I
10.14062/j.issn.0454-5648.20210538
中图分类号
学科分类号
摘要
Combining the photocatalytic activity with the superhydrophobicityof coating is an effective approach for the self-cleaning effect. In this paper, the porous aluminum surface was coated with trialkoxy-terminated polydimethylsiloxane/titanium dioxide (PDMS/TiO2) coating (APT) by a solution immersion method. According to the analysis by Fourier-transformed infrared spectroscopy and X-ray photoelectron spectroscopy, a bond (Ti-O-Si) between PDMS and TiO2 is formed. The results by scanning electron microscopy and energy dispersive spectroscopy show that the superhydrophobicity is due to the interconnected hierarchical sheet structure and the PDMS with a low surface energy. The surface of APT coating has a stable superhydrophobicity with a water contact angle (WCA) of 161.6° and a sliding angle of less than 10°. The stability of superhydrophobicitywith WCAs greater than 150°remains after 24h ultraviolet irradiation. The ATP coating has an effective photocatalytic activity and an ability to degrade dyes and remove some organic substances on the surface. © 2022, Editorial Department of Journal of the Chinese Ceramic Society. All right reserved.
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页码:1275 / 1282
页数:7
相关论文
共 20 条
  • [11] WANG S, LIU K, YAO X, Et al., Bioinspired surfaces with superwettability: New insight on theory, design, and applications, Chem Rev, 115, 16, pp. 8230-8293, (2015)
  • [12] PELAEZ M, NOLAN N T, PILLAI S C, Et al., A review on the visible light active titanium dioxide photocatalysts for environmental applications, Appl Catal B: Environ, 125, pp. 331-349, (2012)
  • [13] QU Y, DUAN X., Progress, challenge and perspective of heterogeneous photocatalysts, Chem Soc Rev, 42, 7, pp. 2568-2580, (2013)
  • [14] WANG Y, HUANG Z, GURNEY R S, Et al., Superhydrophobic and photocatalytic PDMS/TiO<sub>2</sub> coatings with environmental stability and multifunctionality, Colloid Surfaces A, 561, pp. 101-108, (2019)
  • [15] JIANG C, LIU W, YANG M, Et al., Robust multifunctional superhydrophobic fabric with UV induced reversible wettability, photocatalytic self-cleaning property, and oil-water separation via thiol-ene click chemistry, App Surf Sci, 463, pp. 34-44, (2019)
  • [16] CRICK C R, BEAR J C, KAFIZAS A, Et al., Superhydrophobic photocatalytic surfaces through direct incorporation of titania nanoparticles into a polymer matrix by aerosol assisted chemical vapor deposition, Adv Mater, 24, 26, pp. 3505-3508, (2012)
  • [17] KAMEGAWA T, SHIMIZU Y, YAMASHITA H., Superhydrophobic surfaces with photocatalytic self-cleaning properties by nanocomposite coating of TiO<sub>2</sub> and polytetrafluoroethylene, Adv Mater, 24, 27, pp. 3697-3700, (2012)
  • [18] SANGHYUK W N E, DORIS V, AND H B., Stable Hydrophobic metal-oxide photocatalysts via grafting polydimethylsiloxane brush, Adv Mater, 29, pp. 1604637-1604645, (2017)
  • [19] MILLS A, WANG J, LEE S K, Et al., An intelligence ink for photocatalytic films, Chem Commun, 21, 21, pp. 2721-2723, (2005)
  • [20] GHERARDI F, GOIDANICH S, TONIOLO L., Improvements in marble protection by means of innovative photocatalytic nanocomposites, Prog Org Coat, 121, pp. 13-22, (2018)