Dehydration-hydrogen transfer of glycerol to allyl alcohol over bifunctional molybdenum/vanadium-dolomite catalyst

被引：0

作者：

Zhu B. ^{[1
]}

Fu C. ^{[1
]}

Li K. ^{[1
]}

Qiu M. ^{[1
]}

Li C. ^{[1
]}

Zhou C. ^{[1
]}

机构：

[1] College of Chemical Engineering, Zhejiang University of Technology, Hangzhou

来源：

Gao Xiao Hua Xue Gong Cheng Xue Bao/Journal of Chemical Engineering of Chinese Universities | 2023年 / 37卷 / 05期

关键词：

allyl alcohol; dehydration-hydrogen transfer; dolomite; glycerol; molybdenum/vanadium oxide;

D O I：

10.3969/j.issn.1003-9015.2023.05.011

中图分类号：

学科分类号：

摘要：

Bifunctional catalysts MoO/VO-CD-T(CD: calcined dolomite and T: calcined temperature) with both basic sites and redox sites were prepared by impregnation method. The results showed that the molybdenum/vanadium oxides on the catalyst surface were mainly composed of MoO3 and V2O5, and the formation of different phases between calcined dolomite and molybdenum/vanadium oxides could adjust the stability and redox performance of the catalyst. The allyl alcohol was more favorable to be formed over the VO-CD-500 catalyst in air atmosphere, mainly because the oxygen in air could inhibit the reduction of high-valence vanadium. The MoO-CD-500 catalyst had a low activity to allyl alcohol because the reducibility of Mo6+ was weak. 2% VO-CD-500 catalyst showed the best catalytic performance under the condition of 20% glycerol solution and reaction temperature of 320 ℃, with a glycerol conversion of 52.4% and a selectivity to allyl alcohol of 37.4%. © 2023 Zhejiang University. All rights reserved.

引用

页码：787 / 797

页数：10

共 40 条

[21] NIU S L, HUO M J, LU C M, Et al., An investigation on the catalytic capacity of dolomite in transesterification and the calculation of kinetic parameters, Bioresource Technology, 158, pp. 74-80, (2014)
[22] ALGOUFI Y T, KABIR G, HAMEED B H., Synthesis of glycerol carbonate from biodiesel by-product glycerol over calcined dolomite, Journal of the Taiwan Institute of Chemical Engineers, 70, pp. 179-187, (2017)
[23] OCHOA-GOMEZ J R, GOMEZ-JIMENEZ-ABERASTURI O, MAESTRO-MADURGA B, Et al., Synthesis of glycerol carbonate from glycerol and dimethyl carbonate by transesterification: Catalyst screening and reaction optimization, Applied Catalysis A: General, 366, 2, pp. 315-324, (2009)
[24] GUNASEKARAN S, ANBALAGAN G., Spectroscopic study of phase transitions in dolomite mineral, Journal of Raman Spectroscopy, 38, 7, pp. 846-852, (2007)
[25] NUR Z A S, TAUFIQ-YAP Y H, NIZAH M F R, Et al., Production of biodiesel from palm oil using modified Malaysian natural dolomites, Energy Conversion and Management, 78, pp. 738-744, (2014)
[26] SANTILLAN J, WILLIAMS Q, KNITTLE E., Dolomite-II: A high-pressure polymorph of CaMg(CO3)2, Geophysical Research Letters, 30, 2, (2003)
[27] WANG T J, CHANG J, LV P M, Et al., Novel catalyst for cracking of biomass tar, Energy & Fuels, 19, 1, pp. 22-27, (2005)
[28] NIU Y H, SONG Z Z, LI Y K, Et al., Performance research of lanthanum-loaded dolomite catalyst for pine catalytic gasification, Journal of Fuel Chemistry and Technology, 49, 1, pp. 47-54, (2021)
[29] MURGUIA-ORTIZ D, CORDOVA I, MANRIQUEZ M E, Et al., Na-CaO/MgO dolomites used as heterogeneous catalysts in canola oil transesterification for biodiesel production [J], Materials Letters, 291, (2021)
[30] AWADALLAH A E, DEYAB M A, AHMED H A., Mo/MgO as an efficient catalyst for methane decomposition into COx-free hydrogen and multi-walled carbon nanotubes, Journal of Environmental Chemical Engineering, 9, 5, (2021)

← 1 2 3 4 →