Effect of microorganisms in cutting emulsion on corrosion behavior of aluminum alloy

被引:0
|
作者
Shen Y.-Y. [1 ]
Dong Y.-H. [1 ]
Li Q.-H. [1 ]
Zhu H.-L. [1 ]
Dong L.-H. [1 ]
Yin Y.-S. [1 ]
机构
[1] College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai
来源
Surface Technology | 2021年 / 50卷 / 04期
基金
中国国家自然科学基金;
关键词
Accelerated corrosion; Aluminum alloy; Cutting emulsion; EIS; Microorganisms;
D O I
10.16490/j.cnki.issn.1001-3660.2021.04.028
中图分类号
学科分类号
摘要
The work aims to provide theoretical basis for avoiding corrosion of aluminum alloy workpieces during cutting process by studying the effect of microorganisms breed in cutting emulsion on the corrosion behavior and corrosion laws of aluminum alloy. Surface morphology observation and composition analysis methods are used to study the effect of microorganisms on the corrosion morphology of aluminum alloy and the composition of corrosion product, respectively. The distribution of pitting corrosion on the surface of aluminum alloy is analyzed by statistical method. Finally, the electrochemical characteristics of aluminum alloy surface are analyzed by electrochemical method. In the cutting emulsion containing microorganisms, the corrosion of aluminum alloy workpieces is more serious. The surface of the aluminum alloy is attached by microorganisms, forming uneven corrosion product films and biofilms. After removing the film, obvious pitting pits are found, and the number and depth of pitting pits are large, with the deepest reaching 17.7 μm. However, in the sterilized cutting emulsion, only the emulsion is attached to the surface of the aluminum alloy, which is relatively uniform. After removing the film layer, the surface scratches is obvious and no pitting. The electrochemical results also showed that in the cutting emulsion containing multiple microorganisms, the charge transfer resistance Rct of the aluminum alloy decreased gradually from 23 kΩ when immersed for 3 days to 8.3 kΩ after being immersed for 15 days, indicating that the corrosion rate of aluminum alloy significantly increase with time. The growth of microorganisms in the cutting emulsion significantly accelerate the corrosion of the aluminum alloy. © 2021, Chongqing Wujiu Periodicals Press. All rights reserved.
引用
收藏
页码:275 / 284
页数:9
相关论文
共 25 条
  • [11] Muyzer G., Stams A.J.M., The ecology and biotechnology of sulphate-reducing bacteria[J], Nature Reviews Micro-Biology, 6, pp. 441-454, (2008)
  • [12] Dou W W., Jia R., Jin P., Et al., Investigation of the mechanism and characteristics of copper corrosion by sulfate reducing bacteria[J], Corrosion Science, 144, pp. 237-248, (2018)
  • [13] Jia R., Yang D., Xu J., Et al., Microbiologically influenced corrosion of C1018 carbon steel by nitrate reducing Pseu-domonas aeruginosa biofilm under organic carbon starva-tion[J], Corrosion Science, 127, 1-9, (2017)
  • [14] San N.O., Hasan N., Gonul D., Microbiologically influenced corrosion failure analysis of nickel-copper alloy coatings by Aeromonas salmonicida and Delftia acidovorans bacterium isolated from pipe system[J], Engineering Failure Analysis, 25, pp. 63-70, (2012)
  • [15] Zhang Q., He Y., Wang W., Et al., Corrosion behavior of WC-Co hardmetals in the oil-in-water emulsions containing sulfate reducing Citrobacter sp.[J], Corrosion Science, 94, pp. 48-60, (2015)
  • [16] Wang Xiang Z.H.A.N.G.F.-Q., Wu-Hua Y.U.A.N., Et al., Effects of solution time on microstructures and properties of 7050 aluminum alloy[J], Journal of Hunan University (Natural Sciences), 45, 12, pp. 11-14, (2018)
  • [17] Veys-Renaux D., Rocca E., Initial stages of multi-phased aluminium alloys anodizing by MAO: Micro-arc conditions and electrochemical behavior[J], Journal of Solid State Electrochemistry, 19, 10, pp. 3121-3129, (2015)
  • [18] Miranda D.A., Jaimes S.A., Bastidas J.M., Assessment of carbon steel microbiologically induced corrosion by electrical impedance spectroscopy[J], Journal of Solid State Electrochemistry, 18, 2, pp. 389-398, (2014)
  • [19] Becerra H.Q., Retamoso C., Macdonald D.D., The corrosion of carbon steel in oil-in-water emulsions under controlled hydrodynamic conditions[J], Corrosion Science, 42, 3, pp. 561-575, (2000)
  • [20] Rao A C U., Vasu V., Govindaraju M., Et al., Stress corrosion cracking behaviour of 7xxx aluminum alloys: A literature review[J], Transactions of Nonferrous Metals Society of China, 26, 6, pp. 1447-1471, (2016)