Preparation and properties of tannic acid coated abamectin/mesoporous silica nano-pesticide delivery system

被引：0

作者：

Xu P. ^{[1
]}

Dai W. ^{[1
]}

Cao R. ^{[2
]}

Shi W. ^{[3
]}

Xing G. ^{[3
]}

Wang Z. ^{[4
]}

Wang S. ^{[1
]}

Li Q. ^{[1
]}

You Z. ^{[1
]}

Hao D. ^{[4
]}

机构：

[1] College of Chemical Engineering, Nanjing Forestry University, Nanjing

[2] Forest Plant Quarantine Station, Agricultural Technology Promotion Center of Luhe District of Nanjing City, Nanjing

[3] Jiangsu Aijin Crop Technology Group CO., LTD., Nanjing

[4] College of Forestry, Nanjing Forestry University, Nanjing

来源：

Fuhe Cailiao Xuebao/Acta Materiae Compositae Sinica | 2024年 / 41卷 / 03期

关键词：

abamectin; adhesion; anti-photodegradation; mesoporous SiO[!sub]2[!/sub; pesticide delivery system; stimulus response; tannic acid;

D O I：

10.13801/j.cnki.fhclxb.20230828.002

中图分类号：

学科分类号：

摘要：

It is important to increase the retention time of pesticides on the leaf surface of target crops for improving pesticide utilization and reducing the impact of pesticides on the environment. In this paper, we used abamectin (Aba) as a model pesticide and mesoporous silica nanoparticles coated with tannic acid (TA) as a carrier material to construct a nano-pesticide delivery system. Based on the structural and morphological characterization of the nano-pesticide delivery system, we investigated the release performance and foliar adhesion of the nano-pesticide delivery system through simulated release experiments, comparison of contact angle and retention amount on plant foliage and UV photolysis resistance experiments. It is found that tannic acid-coated abamectin-loaded mesoporous silica nanospheres (Aba/MSNs@TA) significantly improve drug wettability on the foliage of Epipremnum aureum, corn and masson pine, and foliar retention is also improved compared to Aba/MSNs. Aba/MSNs@TA exhibits significant pH-responsive release performance, with lower pH environments accelerating the release rate of Aba. In addition, the coating of tannic acid further improves the UV photolytic resistance of the drug in the drug-loaded system. © 2024 Beijing University of Aeronautics and Astronautics (BUAA). All rights reserved.

引用

页码：1470 / 1479

页数：9

共 26 条

[11] GAO Y, XIAO Y, MAO K, Et al., Thermoresponsive polymer-encapsulated hollow mesoporous silica nanoparticles and their application in insecticide delivery[J], Chemical Engineering Journal, 383, (2020)
[12] NEVES J, CARDOSO D N, MALHEIRO C, Et al., Copper toxicity to Folsomia candida in different soils: A comparison between nano and conventional formulations[J], Environmental Chemistry, 16, 6, pp. 419-429, (2019)
[13] ZHAO P, CAO L, MA D, Et al., Translocation, distribution and degradation of prochloraz-loaded mesoporous silica nanoparticles in cucumber plants[J], Nanoscale, 10, 4, pp. 1798-1806, (2018)
[14] SINGH A, DHIMAN N, KAR A K, Et al., Advances in controlled release pesticide formulations: Prospects to safer integrated pest management and sustainable agriculture[J], Journal of Hazardous Materials, 385, (2020)
[15] YIN J, SU X, YAN S, Et al., Multifunctional nanoparticles and nanopesticides in agricultural application[J], Nanomate-rials, 13, 7, (2023)
[16] LI G B, WANG J, KONG X P., Coprecipitation-based synchronous pesticide encapsulation with chitosan for controlled spinosad release[J], Carbohydrate Polymers, 249, (2020)
[17] ZIVAN O, SEGAL-ROSENHEIMER M, DUBOWSKI Y., Airborne organophosphate pesticides drift in mediterranean climate: The importance of secondary drift[J], Atmospheric Environment, 127, pp. 155-162, (2016)
[18] SCHOLTZ M T, BIDLEMAN T F., Modelling of the long-term fate of pesticide residues in agricultural soils and their surface exchange with the atmosphere: Part II. Projected long-term fate of pesticide residues[J], Science of the Total Environment, 377, 1, pp. 61-80, (2007)
[19] SINGH H, SHARMA A, BHARDWAJ S K, Et al., Recent advances in the applications of nano-agrochemicals for sustainable agricultural development[J], Environmental Science: Processes & Impacts, 23, 2, pp. 213-239, (2021)
[20] LIANG Y, FAN C, DONG H, Et al., Preparation of MSNs-chitosan@prochloraz nanoparticles for reducing toxicity and improving release properties of prochloraz[J], ACS Sustainable Chemistry & Engineering, 6, 8, pp. 10211-10220, (2018)

← 1 2 3 →