Syntheses, Structures, Properties, and Calculation of a Family of Ionic Crystals Based on 1,3-bis(5-tetrazolyl)triazene

被引：0
|
作者：
He, Liang [1 ]
Shi, Zi-chen [1 ]
Huang, Wen-hui [1 ]
Xue, Qi [2 ]
Yang, Jian-hui [1 ]
Liu, Bin [1 ]
机构：
[1] Northwest Univ, Coll Chem & Mat Sci, Key Lab Synthet & Nat Funct Mol, Minist Educ, Xian 710127, Peoples R China
[2] China North Ind Grp Corp Ltd, Xian Modern Chem Res Inst, Xian 710065, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2024年 / 650卷 / 22期
基金：
中国国家自然科学基金;
关键词：
Energetic materials; 1,3-Bis(5-tetrazolyl)triazene; Ionic crystal; TG-DSC; COORDINATION; PERFORMANCE; SUBSTITUTION; COMPLEXES;
D O I：
10.1002/zaac.202400049
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Sodium salt of 1,3-bis(5-tetrazolyl)triazene (NaH2BTT & sdot; 4H2O) was obtained through diazo-couple reaction with 5-aminotetrazole as starting reactants, and a family of energetic ionic crystals of the 1,3-bis(5-tetrazolyl)triazene anions HnBTT(3-n)- with different cations were investigated, including protonated amines (ethanediamine, hydrazinium, aminoguanidine, methylhydrazinium) and Y(H2O)83+. The structures and physicochemical properties of these compounds were characterized by IR, Raman, X-ray diffraction (XRPD) and TG-DSC. Ethanediamine salt is the best thermal stable, while hydrazinium salt possesses a highest nitrogen rich value of 79.76 %. Both of them show a rapid collapse of the BTT main frame, and almost all of the dissociation products are released in the form of gas. image
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页数：7
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