Modeling investigation on biomass gasification coupled with chemical looping oxygen uncoupling

被引：0
|
作者：
Wang, Kun [1 ,2 ,3 ]
Ran, Zezhou [1 ,3 ]
Zhao, Shengnan [1 ,2 ]
Wu, Haoyang [2 ,3 ]
机构：
[1] National Frontiers Science Center for Industrial Intelligence and Systems Optimization, Northeastern University, Shenyang,110819, China
[2] Key Laboratory of Data Analytics and Optimization for Smart Industry (Northeastern University), Ministry of Education, China
[3] School of Metallurgy, State Environmental Protection Key Laboratory of Eco-Industry, Northeastern University, Shenyang,110819, China
来源：
International Journal of Hydrogen Energy | 2024年 / 96卷
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
In this study; the integrated dynamic model of biomass gasification and chemical looping oxygen uncoupling process was established. In view of the significant influence of carbon surface heterogeneous reaction kinetics on process performance; the RCstr module was used to simulate the gasification reaction; and the dynamics parameters were directly integrated into Aspen Plus by writing an external Fortran subroutine. This method overcame the limitation caused by the traditional RGibbs module only considering thermodynamic factors; realized the comprehensive coupling of dynamics and thermodynamic factors; significantly improved the accuracy and reliability of simulation results. The effects of steam biomass ratio (S/B); equivalent ratio (ER); pressure and temperature on syngas quality were further investigated. The results showed that the optimal reaction conditions included S/B = 0.036; ER; 0.3; P; 1; atm; T = 1000 K with a carbon conversion rate close to 100% and calorific value of 11772 kJ/Nm3; the cold gas efficiency reached 47.93%. Finally; energy analysis and exergy analysis were conducted; which revealed that low temperature along with appropriate ER and low S/B can effectively reduce overall energy consumption. Under optimal conditions; the energy consumption and exergy efficiency were 28.744 MJ and 52.33% respectively. Exergy loss was primarily caused by the irreversibility of pyrolysis and gasification processes. © 2024 Hydrogen Energy Publications LLC;
D O I：
10.1016/j.ijhydene.2024.11.314
中图分类号：
学科分类号：
摘要：
引用
收藏
页码：360 / 368
相关论文
共 50 条
  • [31] Biomass chemical looping gasification for syngas production using modified hematite as oxygen carriers
    Cong Jiang
    Xiaoyu Jin
    Tingting Xu
    Bo Xiao
    Zhiquan Hu
    Xun Wang
    Journal of Environmental Sciences, 2023, (03) : 171 - 184
  • [32] Comprehensive performance investigation of inexpensive oxygen carrier in chemical looping gasification of coal
    Wang, Yanan (ynwang@cczu.edu.cn); Zhao, Haibo (hzhao@mail.hust.edu.cn), 2025, 118
  • [33] CFD investigation of the in-situ gasification process of biomass in the chemical looping combustion system
    Dong, Ruihan
    Yang, Shiliang
    Hu, Jianhang
    Chen, Fangjun
    Bao, Guirong
    Wang, Hua
    RENEWABLE ENERGY, 2022, 185 : 1245 - 1260
  • [34] Numerical investigation of in situ gasification chemical looping combustion of biomass in a fluidized bed reactor
    Yin, Weijie
    Wang, Shuai
    Zhang, Kai
    He, Yurong
    RENEWABLE ENERGY, 2020, 151 : 216 - 225
  • [35] Behavior of mercury in chemical looping with oxygen uncoupling of coal
    Ma, Jinchen
    Tian, Xin
    Zhao, Bo
    Li, Xiaoshan
    Zhao, Yongchun
    Zhao, Haibo
    Zheng, Chuguang
    FUEL PROCESSING TECHNOLOGY, 2021, 216
  • [36] An investigation of steam production in chemical-looping combustion (CLC) and chemical-looping with oxygen uncoupling (CLOU) for solid fuels
    Dansie, J. K.
    Sahir, A. H.
    Hamilton, M. A.
    Lighty, J. S.
    CHEMICAL ENGINEERING RESEARCH & DESIGN, 2015, 94 : 12 - 17
  • [37] Investigation on gasification performance of sewage sludge using chemical looping gasification with iron ore oxygen carrier
    Huang, Zhen
    Xu, Genli
    Deng, Zhengbing
    Zhao, Kun
    He, Fang
    Chen, Dezhen
    Wei, Guoqiang
    Zheng, Anqing
    Zhao, Zengli
    Li, Haibin
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (40) : 25474 - 25491
  • [38] Natural iron ore as an oxygen carrier for biomass chemical looping gasification in a fluidized bed reactor
    Huang, Zhen
    He, Fang
    Zhao, Kun
    Feng, Yipeng
    Zheng, Anqing
    Chang, Sheng
    Zhao, Zengli
    Li, Haibin
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2014, 116 (03) : 1315 - 1324
  • [39] Natural iron ore as an oxygen carrier for biomass chemical looping gasification in a fluidized bed reactor
    Zhen Huang
    Fang He
    Kun Zhao
    Yipeng Feng
    Anqing Zheng
    Sheng Chang
    Zengli Zhao
    Haibin Li
    Journal of Thermal Analysis and Calorimetry, 2014, 116 : 1315 - 1324
  • [40] Biomass gasification using chemical looping in a 25 kWth reactor with natural hematite as oxygen carrier
    Ge, Huijun
    Guo, Wanjun
    Shen, Laihong
    Song, Tao
    Xiao, Jun
    CHEMICAL ENGINEERING JOURNAL, 2016, 286 : 174 - 183
12345