Crystal structures of the R1.33 Ni3 Ga8 (R = Tb, Ho, Er, Tm, Lu) compounds

被引：0

作者：

Muts, Nataliya ^{[1
]}

Tokaychuk, Yaroslav ^{[1
]}

Gladyshevskii, Roman ^{[1
]}

机构：

[1] Ivan Franko Natl Univ Lviv, Dept Inorgan Chem, Kyryla i Mefodiya St 6, UA-79005 Lvov, Ukraine

来源：

SOLID STATE SCIENCES | 2024年 / 158卷

关键词：

X-ray powder diffraction; Energy-dispersive X-ray spectroscopy; Crystal structure; Homologous structure series; Gd 1.33 Pt 3 Al 8 structure type; GD; DY;

D O I：

10.1016/j.solidstatesciences.2024.107737

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The existence of five new ternary compounds with Gd1.33Pt3Al8-type structure (Pearson symbol hR 51, space group R- 3 m ) was established by means of X-ray powder diffraction and energy-dispersive X-ray spectroscopy: Tb1.33Ni3Ga8 (& acy; = 4.2056(1), & scy; = 37.8913(9) & Aring;), Ho1.33Ni3Ga8 (& acy; = 4.19666(9), & scy; = 37.7882(9) & Aring;), Er1.33Ni3Ga8 (a = 4.19290(8), c = 37.7446(8) & Aring;), Tm1.33Ni3Ga8 (a = 4.18819(7), c = 37.6980(7) & Aring;), and Lu1.33Ni3Ga8 (a = 4.1826(1), c = 37.647(1) & Aring;). The structures of the ternary R 1.33 Ni 3 Ga 8 compounds belong to a family of linearintergrowth structures with the general formula R 0.67 T n M 2 n + m and are built from atom layers of the composition R 0.67 Ga ( R 0.67 M ), separated by single or double NiGa2 slabs (TM2). The layers containing the rare-earth metal atoms are characterized by a disordered distribution of rare-earth metal atoms and Ga-atom triangles.

引用

页数：8

共 50 条

[41] CRYSTAL STRUCTURES OF LUMN5 AND RMN12 COMPOUNDS (WHERE R = GD TB DY HO ER AND TM)
WANG, FE
GILFRICH, JV
ACTA CRYSTALLOGRAPHICA, 1966, 21 : 476 - &
[42] CENI3-TYPE TERNARY PHASES IN THE R-NI-GA SYSTEMS (R-Y, PR, ND, SM, GD, TB, DY, HO, ER, TM, YB, LU)
WASYLECHKO, LO
GRIN, YN
FEDORCHUK, AA
JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 219 : 222 - 224
[43] CRYSTAL-STRUCTURE OF RGANI COMPOUNDS (R=CE,PR,ND,SM,GD,TB,DY,HO,ER,TM,YB,LU,Y)
YARMOLYUK, YP
GRYN, YN
GLADYSHEVSKY, EI
DOPOVIDI AKADEMII NAUK UKRAINSKOI RSR SERIYA A-FIZIKO-MATEMATICHNI TA TECHNICHNI NAUKI, 1979, (09): : 771 - 775
[44] MAGNETOCRYSTALLINE ANISOTROPY OF OF R(2)FE(10)GA(7) COMPOUNDS WITH R=Y, SM, GD, TB, DY, HO, ER AND TM
SHEN, BG
CHENG, ZH
LIANG, B
GONG, HY
ZHANG, JX
YAN, QW
ZHAN, WS
SOLID STATE COMMUNICATIONS, 1995, 96 (11) : 859 - 863
[45] Crystal structure of RCu5-xPbx (R=Y, Gd, Tb, Dy, Ho, Er, Tm, Lu) phases
Gulay, LD
JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 314 (1-2) : 206 - 208
[46] Synthesis and Crystal Structures of New RRuxGa1-x (R = Er, Tm, Lu) Gallides and R2Ru1-xIn1+x (R = Dy, Ho, Er, Tm, Lu) Indides
Sedelnikov, D., V
Grishina, Yu A.
Tursina, A., I
Kurenbaeva, Zh M.
Murashova, E., V
INORGANIC MATERIALS, 2022, 58 (06) : 568 - 577
[47] Crystal structures of the R2Pb3Sn3S12 (R = La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er and Tm) compounds
Gulay, L.D.
Ruda, I.P.
Marchuk, O.V.
Olekseyuk, I.D.
Journal of Alloys and Compounds, 2008, 457 (1-2): : 204 - 208
[48] Crystal structures of the R2Pb3Sn3S12 (R = La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er and Tm) compounds
Gulay, L. D.
Ruda, I. P.
Marchuk, O. V.
Olekseyuk, I. D.
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 457 (1-2) : 204 - 208
[49] Anisotropic magnefization studies of R2CoGa8 single crystals (R = Gd, Tb, Dy, Ho, Er, Tm, Y, and Lu)
Joshi, Devang A.
Nagalakshmi, R.
Dhar, S. K.
Thamizhavel, A.
PHYSICAL REVIEW B, 2008, 77 (17):
[50] Magnetic structures of the R2Ni3Si5 compounds (R=Tb, Dy, Ho)
Szytula, A
Kolenda, M
Ressouche, E
PHYSICA B, 1997, 234 : 663 - 664

← 1 2 3 4 5 →