Microwave dielectric properties of Li2Mg2Ga2Ti3O12 ceramics with spinel-type

被引:0
|
作者
Jiang, Chang [1 ]
Ma, Linzhao [1 ]
Tian, Guo [1 ]
Jiang, Longxiang [1 ]
Xiao, Hongzhi [1 ]
Du, Qianbiao [1 ]
Li, Hao [1 ]
机构
[1] Hunan Univ, Coll Elect & Informat Engn, Changsha 410082, Peoples R China
基金
中国国家自然科学基金;
关键词
Microwave dielectric ceramics; Spinel structure; P -V-L theory; CRYSTAL-STRUCTURE; SINTERING TEMPERATURE; BOND CHARACTERISTICS; COMPOSITE CERAMICS; PHASE EVOLUTION; BEHAVIOR; QUALITY; TAU(F); CATION; CA;
D O I
10.1016/j.ceramint.2024.08.441
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Novel spinel-type Li2Mg2Ga2Ti3O12 ceramics were prepared by the solid-state method. Rietveld refinement revealed that the Li2Mg2Ga2Ti3O12 ceramics possess a cubic spinel structure with the Fd3m(227) space group. Raman spectrum analysis indicated that the Q x f and FWHM of ceramics exhibit an inverse relationship. According to the P-V-L theory, the Ti-O bond has the highest percentage of contribution to both of bond ionicity and lattice energy, indicating a significant impact on r pound and Q x f, respectively. The Li2Mg2Ga2Ti3O12 ceramics showed the best microwave dielectric properties (r pound = 15.72, Q x f = 69,633 GHz, and of = -20 ppm/degrees C), sintering at an optimum temperature of 1200 degrees C. Additionally, a dielectric resonance antenna, on the basis of Li2Mg2Ga2Ti3O12 ceramics was designed and simulated.
引用
收藏
页码:46002 / 46007
页数:6
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