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Microwave dielectric properties of Li2Mg2Ga2Ti3O12 ceramics with spinel-type
被引:0
|作者:
Jiang, Chang
[1
]
Ma, Linzhao
[1
]
Tian, Guo
[1
]
Jiang, Longxiang
[1
]
Xiao, Hongzhi
[1
]
Du, Qianbiao
[1
]
Li, Hao
[1
]
机构:
[1] Hunan Univ, Coll Elect & Informat Engn, Changsha 410082, Peoples R China
基金:
中国国家自然科学基金;
关键词:
Microwave dielectric ceramics;
Spinel structure;
P -V-L theory;
CRYSTAL-STRUCTURE;
SINTERING TEMPERATURE;
BOND CHARACTERISTICS;
COMPOSITE CERAMICS;
PHASE EVOLUTION;
BEHAVIOR;
QUALITY;
TAU(F);
CATION;
CA;
D O I:
10.1016/j.ceramint.2024.08.441
中图分类号:
TQ174 [陶瓷工业];
TB3 [工程材料学];
学科分类号:
0805 ;
080502 ;
摘要:
Novel spinel-type Li2Mg2Ga2Ti3O12 ceramics were prepared by the solid-state method. Rietveld refinement revealed that the Li2Mg2Ga2Ti3O12 ceramics possess a cubic spinel structure with the Fd3m(227) space group. Raman spectrum analysis indicated that the Q x f and FWHM of ceramics exhibit an inverse relationship. According to the P-V-L theory, the Ti-O bond has the highest percentage of contribution to both of bond ionicity and lattice energy, indicating a significant impact on r pound and Q x f, respectively. The Li2Mg2Ga2Ti3O12 ceramics showed the best microwave dielectric properties (r pound = 15.72, Q x f = 69,633 GHz, and of = -20 ppm/degrees C), sintering at an optimum temperature of 1200 degrees C. Additionally, a dielectric resonance antenna, on the basis of Li2Mg2Ga2Ti3O12 ceramics was designed and simulated.
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页码:46002 / 46007
页数:6
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