Degradation of Rhodamine B by Visible Light Driven MoO3@TiO2 Core-Shell Photocatalyst

被引:0
|
作者
Liu, Hejin [1 ]
Qiao, Peng [1 ]
Liu, Ying [3 ]
Guo, Xin [1 ]
Liu, Yanxiu [1 ]
Song, Hua [1 ]
Wang, Xueqin [1 ]
Wang, Wenyi [2 ]
机构
[1] Northeast Petr Univ, Coll Chem & Chem Engn, Prov Key Lab Oil & Gas Chem Technol, Daqing 163318, Peoples R China
[2] Daqing Normal Univ, Sch Chem Engn, Heilongjiang Prov Key Lab Oilfield Appl Chem & Tec, Daqing 163712, Peoples R China
[3] Jiangyin Sr High Sch Jiangsu Prov, Jiangyin 214000, Peoples R China
基金
中国国家自然科学基金;
关键词
ROUTE; WATER;
D O I
10.1021/acs.langmuir.4c03333
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, a MoO3@TiO2 composite core-shell material was developed to remove Rhodamine B (RhB) dye through synergistic adsorption and photocatalytic degradation. n-n heterostructures were formed by coupling n-type semiconductors to enhance the efficiency of photocarrier separation and photocatalytic performance. MoO3, which possesses strong adsorption capacity, was primarily used as a dye adsorbent. Additionally, the formation of an n-n heterojunction with TiO2 enabled MoO3 to expand the photocorresponding range of TiO2, leading to the generation of superoxide (O2 center dot) and hydroxyl (center dot OH) free radicals for dye degradation. The experimental results demonstrate that the MoO3@TiO2 core-shell composite exhibits excellent performance for RhB dye removal, with adsorption and degradation rates reaching 35.7 and 70.3%, respectively, even at low catalyst concentrations. This approach offers new insights into the development of MoO3 core-shell photocatalysts.
引用
收藏
页码:24029 / 24036
页数:8
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