Effects of sulfurization temperature on CZTS thin film solar cell performances

被引：0

作者：

机构：

[1] Emrani, Amin

[2] Vasekar, Parag

[3] Westgate, Charles R.

来源：

Emrani, A. (amin.emrani@gmail.com) | 2013年 / Elsevier Ltd卷 / 98期

关键词：

Deposition - II-VI semiconductors - Scanning electron microscopy - Thin films - X ray diffraction - Magnetrons - Tin compounds - Energy dispersive spectroscopy - Zinc oxide - Cadmium sulfide - Copper compounds;

D O I：

10.1016/j.solener.2013.09.020

中图分类号：

学科分类号：

摘要：

Synthesis of Cu2ZnSnS4 thin film solar cells by sulfurization of sputtered Sn/Zn/Cu precursors is studied. The sulfurization temperatures were varied, and the morphology, cross section, and composition of the CZTS were investigated by scanning electron microscopy, energy dispersive spectroscopy, X-ray diffraction and Raman scattering. To further explore the CZTS layer, the following additional layers were deposited to complete the solar cells: CdS with chemical bath deposition; ZnO and AZO with RF magnetron deposition; and, finally, silver fingers as the front contact. The efficiency and characteristics of the thin film solar cells were measured and a detailed comparison is reported. Sulfurization at 550°C yields a maximum efficiency of 5.75% without any anti-reflective layers. © 2013 Elsevier Ltd.

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