Synthesis and optical properties of poly[(2-alkoxy-5-methyl-1,3-phenyleneethynylene)-alt-(1,3- phenyleneethynylene)]s

被引：0
|
作者：
Chu, Qinghui [1 ]
Pang, Yi [1 ]
机构：
[1] Department of Chemistry, Center for High Performance Polymers and Composites, Clark Atlanta University, Atlanta, GA 30314, United States
来源：
Synthesis | 2002年 / 09期
关键词：
Absorption - Electron emission - Fluorescence - Optical properties - Polymers - Quantum efficiency - Spectroscopic analysis;
D O I：
10.1055/s-2002-32528
中图分类号：
学科分类号：
摘要：
A few examples of poly(m-phenyleneethynylene)s 6 and 9 have been synthesized via Heck-coupling reaction. With the aid of the model compound, the optical band structures of the electronic absorption and emission spectra have been characterized by using UV-Vis and fluorescence spectroscopy at variable temperatures. While both polymers 6 and 9 are blue-emitting in the solid state, the solution quantum efficiency of the former (φfl ≅ 0.34) is about twice as higher as that of the latter (φfl ≅ 0.15).
引用
收藏
页码：1261 / 1267
相关论文
共 50 条
  • [41] Synthesis and properties of novel biodegradable triblock copolymers of poly(5-methyl-5-methoxycarbonyl-1,3-dioxan-2-one) and poly(ethylene glycol)
    Zhou, Y
    Zhuo, RX
    Liu, ZL
    POLYMER, 2004, 45 (16) : 5459 - 5463
  • [42] SYNTHESIS AND MESOMORPHOUS PROPERTIES OF CIS-2-ALKYL-5-METHYL-5-CARBOXY-1,3-DIOXANES AND TRANS-2-ALKYL-5-METHYL-5-CARBOXY-1,3-DIOXANES AND THEIR DERIVATIVES
    BEZBORODOV, VS
    ZHURNAL ORGANICHESKOI KHIMII, 1989, 25 (02): : 377 - 379
  • [43] (Z)-N-{3-[(2-Chloro-1,3-thiazol-5-yl)methyl]-1,3-thiazolidin-2-ylidene}cyanamide
    Li, Yue-Ming
    Li, Jian-Ye
    Wang, Qian
    Hao, Ai-You
    Sun, Tao
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O3303 - U1474
  • [44] Efficient blue-green-emitting poly[(5-diphenylamino-1, 3-phenylenevinylene)-alt-(2,5-dihexyloxy-1, 4-phenylenevinylene)] derivatives:: Synthesis and optical properties
    Liao, L
    Cirpan, A
    Ding, LM
    Karasz, FE
    Pang, Y
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (07) : 2307 - 2315
  • [45] PROPERTIES AND REACTIONS OF 1,3-OXATHIOLANES .3. CONFORMATIONAL ENERGIES AND MOST PROBABLE CONFORMATIONS OF 2-ALKYL-5-METHYL-1,3-OXATHIOLANES AND 2,2-DIALKYL-5-METHYL-1,3-OXATHIOLANES
    KESKINEN, R
    PIHLAJA, K
    NIKKILA, A
    TETRAHEDRON, 1972, 28 (14) : 3943 - &
  • [46] SYNTHESIS OF 4-ALKOXY-1,3-OXAZOL-5(2H)-ONES, PRECURSORS OF 1-ALKOXY-SUBSTITUTED NITRILE YLIDES
    BOZHKOVA, N
    HEIMGARTNER, H
    HELVETICA CHIMICA ACTA, 1989, 72 (04) : 825 - 837
  • [47] (S)-methyl 2-(1,3-dioxoisoindolin-2-yl)-3-(4-iodophenyl) propionate
    Wu, Zhou
    Shen, Peng
    Jiang, Shende
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O4871 - U6581
  • [48] The effect of crystallization properties influenced by 2-methyl-1,3-propanediol units on the optical properties of modified poly(ethylene terephthalate)
    Wang, Qiu-xia
    Zhang, Fu-chen
    Qu, De-zhi
    Bai, Yong-ping
    HIGH PERFORMANCE POLYMERS, 2019, 31 (02) : 211 - 219
  • [49] SYNTHESIS OF POLY[1,3-DIPHENYL-5-(P-VINYLPHENYL)-2-PYRAZOLINE]
    Iinuma, F
    MIKAWA, H
    SHIROTA, Y
    POLYMER BULLETIN, 1979, 1 (05) : 315 - 318
  • [50] SYNTHESIS, PHOTOCHROMISM PROPERTIES OF 1-(2-METHYL-1-THIENYL)-2-[2-METHYL-5-(1,3-DIOXOLANE)-3-THIENYL] PERFLUOROCYCLOPENTENE
    Li, Gang
    Liu, Gang
    Zhang, Dao-Bin
    MATERIAL ENGINEERING AND MECHANICAL ENGINEERING (MEME2015), 2016, : 1476 - 1480
12345