Synthesis and optical properties of poly[(2-alkoxy-5-methyl-1,3-phenyleneethynylene)-alt-(1,3- phenyleneethynylene)]s

被引：0

作者：

Chu, Qinghui ^{[1
]}

Pang, Yi ^{[1
]}

机构：

[1] Department of Chemistry, Center for High Performance Polymers and Composites, Clark Atlanta University, Atlanta, GA 30314, United States

来源：

Synthesis | 2002年 / 09期

关键词：

Absorption - Electron emission - Fluorescence - Optical properties - Polymers - Quantum efficiency - Spectroscopic analysis;

D O I：

10.1055/s-2002-32528

中图分类号：

学科分类号：

摘要：

A few examples of poly(m-phenyleneethynylene)s 6 and 9 have been synthesized via Heck-coupling reaction. With the aid of the model compound, the optical band structures of the electronic absorption and emission spectra have been characterized by using UV-Vis and fluorescence spectroscopy at variable temperatures. While both polymers 6 and 9 are blue-emitting in the solid state, the solution quantum efficiency of the former (φfl ≅ 0.34) is about twice as higher as that of the latter (φfl ≅ 0.15).

引用

页码：1261 / 1267

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