Mathematical modeling of polystyrene particle size distribution produced by suspension polymerization

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作者
Machado, R.A.F.
Pinto, J.C.
Araujo, P.H.H.
Bolzan, A.
机构
[1] Prog. de Engenharia Química, COPPE, Univ. Federal do Rio de Janeiro, C.P. 68502, CEP 21945-970, Rio de Janeiro, RJ, Brazil
[2] Depto. Engenharia Quim. de Alimentos, CTC, Univ. Federal de Santa Catarina, C.P. 476, CEP 88010-970, Florianopolis, SC, Brazil
[3] Depto. de Engenharia Química, Escola Politécnica, Universidade de São Paulo, CEP 05508-900, São Paulo - SP, Brazil
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Particle size distribution (PSD) of polystyrene particles produced by suspension polymerization is of fundamental importance in determining suspension stability and product quality attributes. Within a population balance framework, a model is proposed for suspension polymerization reactors to describe the evolution of the PSD. The model includes description of breakage and coalescence rates in terms of reaction kinetics and rheology of the dispersed phase. The model is validated with experimental data of styrene suspension polymerization.
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页码:395 / 405
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