Structural Features and Properties of Sodium-Rubidium Aluminoborosilicate Glasses with Zirconium

被引：0

作者：

Eremyashev, V. E. ^{[1
]}

Korinevskaya, G. G. ^{[1
]}

Zhivulin, D. E. ^{[2
]}

Bocharov, V. N. ^{[3
]}

机构：

[1] Russian Acad Sci, South Urals Fed Res Ctr Mineral & Geoecol, Ural Branch, Miass, Chelyabinsk Obl, Russia

[2] South Ural State Univ, Natl Res Univ, Chelyabinsk, Russia

[3] St Petersburg Univ, St Petersburg, Russia

来源：

GLASS AND CERAMICS | 2024年 / 81卷 / 7-8期

关键词：

aluminoborosilicate glass; spectroscopy; structure; thermal properties; radioactive waste; vitrification; zirconium; BOROSILICATE GLASSES;

D O I：

10.1007/s10717-024-00703-z

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

By means of vibrational spectroscopy, the study examines the structure of matrix materials synthesized through the quenching of sodium-rubidium aluminoborosilicate melts with the addition of zirconium. Zirconium was found to have a significant effect on the ratio of the main structural units and the distribution of modifier cations among them in the glass structure. The obtained results were used to explain changes in the glass-melt transition temperature and synthesized material density; they can be useful in adjusting the composition and synthesis parameters of matrix materials for the immobilization of high-level radioactive waste containing significant amounts of zirconium.

引用

页码：309 / 314

页数：6

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