Preparation, characterization, and activation of Co-Mo/Y zeolite catalyst for coal tar conversion to liquid fuel

被引:7
|
作者
Anggoro D.D. [1 ]
Buchori L. [1 ]
Silaen G.C. [1 ]
Utami R.N. [1 ]
机构
[1] Chemical Engineering Department, Diponegoro University, Jl. Prof. Soedarto, Tembalang, Semarang
来源
Anggoro, Didi Dwi (anggorophd@gmail.com) | 1600年 / Diponegoro University卷 / 12期
关键词
Catalyst activation; Catalyst characterization; Catalyst preparation; Co-Mo/Y zeolite; Coal tar;
D O I
10.9767/bcrec.12.2.768.219-226
中图分类号
学科分类号
摘要
One of many efforts to convert coal tar into alternative liquid fuel is by hydrocracking. This research aims to determine the impregnation of Co-Mo/Y zeolite, its characteristics, the effect of impregnation temperature and time, and also the best Co-Mo/Y zeolite impregnation condition for the conversion of coal tar. This research was conducted in several steps, impregnating Co from Co(NO3)2.6H2O and Mo from (NH4)6Mo7O24.4H2O into Zeolite Y in liquid media, drying at 100°C for 24 hours, and calcination at 550°C for 3 hours. Coal tar was then reacted with hydrogen gas (as a reactant), and Co-Mo/Zeolite Y (as a catalyst) was conducted at 350°C. Characteristic analysis showed that Co and Mo had impreg-nated into the Y zeolite, as well as it made no change of catalyst's structure and increased the total acidity. The higher of impregnation temperature was increased the catalyst crystallinity, total acidity, and yield of gasoline. The longer impregnation time was reduced crystallinity value, but total acidity and yield were increased. GC analysis showed that products included into the gasoline product (C8, C9, and C10). Copyright © 2017 BCREC Group. All rights reserved.
引用
收藏
页码:219 / 226
页数:7
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