Hexathienocoronenes: Synthesis and self-organization

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作者：

Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany ^{[1
]}

不详 ^{[2
]}

机构：

[1] Chen, Long

[2] Puniredd, Sreenivasa R.

[3] Tan, Yuan-Zhi

[4] Baumgarten, Martin

[5] Zschieschang, Ute

[6] Enkelmann, Volker

[7] Pisula, Wojciech

[8] Feng, Xinliang

[9] Klauk, Hagen

[10] Müllen, Klaus

来源：

Müllen, K. (muellen@mpip-mainz.mpg.de) | 1600年 / American Chemical Society卷 / 134期

关键词：

Here we report hexathienocoronenes (HTCs); fully thiophene-annelated coronenes in which six double bonds in the periphery are thieno-fused. The derivatives tetrasubstituted with hexyl and dodecyl chains show a phase formation that strongly depends on the chain length. HTCs are remarkably stronger donors than the known thiophene-annelated coronenes but do not readily assemble into well-ordered films when deposited from the vapor phase. Thus; thin-film transistors fabricated by vacuum deposition have only modest field-effect mobilities of 0.002 cm2 V-1 s-1. © 2012 American Chemical Society;

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