Synthesis of Li3V2 (PO4)3 by low temperature carbothermal reduction method and its electrochemical properties

被引：0
|
作者：
Zhong, Shengkui [1 ,2 ]
Yin, Zhoulan [1 ]
Liu, Jiequn [1 ,2 ]
Chen, Qiyuan [1 ]
机构：
[1] Central South University, Changsha 410083, China
[2] Guilin University of Technology, Guilin 541004, China
来源：
Xiyou Jinshu Cailiao Yu Gongcheng/Rare Metal Materials and Engineering | 2008年 / 37卷 / 09期
关键词：
Electrochemical properties - Electric discharges - Carbothermal reduction - Lithium-ion batteries - Vanadium pentoxide - Cathodes - Lithium compounds;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Li3V2 (PO4)3 cathode material was prepared by a low temperature carbothermal reduction reaction of V2O5·nH2O hydro-gel, LiOHH2O, NH4H2PO4 and C. The effect of reaction temperature and time on the structure, morphology and electrochemical properties was investigated. The results show that the sample synthesized at 550C for 12 h has a single monoclinic structure with homogenous distribution of particle, which derives a initial discharge capacity of 130 mAhg-1 at 0.2 C rate, and the capacity retains 124 mAhg-1 after 30 cycles.
引用
收藏
页码：1652 / 1655
相关论文
共 50 条
  • [21] High rate capability of Li3V2(PO4)3/C composites prepared via a TPP-assisted carbothermal method and its application in Li3V2(PO4)3||Li4Ti5O12
    Mao, Wen-feng
    Zhang, Nuo-nuo
    Tang, Zhi-yuan
    Feng, Ya-qing
    Ma, Chen-xiang
    JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 588 : 25 - 29
  • [22] Li3V2(PO4)3:: Synthesis by sol-gel method and performance
    Dai Chang-Song
    Wang Fu-Ping
    Liu Jing-Tao
    Wang Dian-Long
    Hu Xin-Guo
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2008, 24 (03) : 381 - 387
  • [23] A study of the electrochemical behavior at low temperature of the Li3V2(PO4)3 cathode material for Li-ion batteries
    Tai, Ling-Hua
    Zhao, Qin
    Sun, Li-Qun
    Cong, Li-Na
    Wu, Xing-Long
    Zhang, Jing-Ping
    Wang, Rong-Shun
    Xie, Hai-Ming
    Chen, Xiao-Hong
    NEW JOURNAL OF CHEMISTRY, 2015, 39 (12) : 9617 - 9626
  • [24] Mn-doped Li3V2(PO4)3 nanocrystal with enhanced electrochemical properties based on aerosol synthesis method
    Chunyan Lai
    Zheng Chen
    Huihui Zhou
    Yunfeng Lu
    Hexing Li
    Journal of Materials Science, 2015, 50 : 3075 - 3082
  • [25] Synthesis and electrochemical performance study of Li3V2(PO4)3 by a microwave sol-gel method
    Zhong, Sheng-Kui, 1600, Northeast University (35):
  • [26] Controllable synthesis of spherical Li3V2(PO4)3/C cathode material and its electrochemical performance
    Zhang, Lu-Lu
    Peng, Gang
    Liang, Gan
    Zhang, Peng-Chang
    Wang, Zhao-Hui
    Jiang, Yan
    Huang, Yun-Hui
    Lin, Hao
    ELECTROCHIMICA ACTA, 2013, 90 : 433 - 439
  • [27] Synthesis and electrochemical performance of Li3V2(PO4)3/C by organic solvent replacement drying method
    Xiushan Yang
    Yan Tang
    Yanjun Zhong
    Benhe Zhong
    Xiaodong Guo
    Zhuo Zheng
    Ionics, 2018, 24 : 385 - 391
  • [28] Mn-doped Li3V2(PO4)3 nanocrystal with enhanced electrochemical properties based on aerosol synthesis method
    Lai, Chunyan
    Chen, Zheng
    Zhou, Huihui
    Lu, Yunfeng
    Li, Hexing
    JOURNAL OF MATERIALS SCIENCE, 2015, 50 (08) : 3075 - 3082
  • [29] Synthesis and electrochemical properties of Ti-doped Li3V2(PO4)3/C cathode materials
    Sheng-Kui Zhong
    You Wang
    Ling Wu
    Jie-Qun Liu
    Rare Metals, 2015, 34 : 586 - 589
  • [30] Synthesis and electrochemical performance of 3LiMnPO4·Li3V2 (PO4)3 cathode material
    Guangxi Key Laboratory of New Energy and Building Energy Saving, Guilin University of Technology, Guilin, China
    不详
    Rengong Jingti Xuebao, 2 (464-469):
12345