Synthesis, properties and dimerization study of isocyanic acid

被引:0
|
作者
Fischer, Gerd [1 ]
Geith, Janna [1 ]
Klapötke, Thomas M. [1 ]
Krumm, Burkhard [1 ]
机构
[1] Department of Chemistry, University of Munich (LMU), Butenandtstrasse 5 - 13 (D), D-81377 Munich, Germany
关键词
Nuclear magnetic resonance spectroscopy - Sodium compounds - Thermodynamic stability - Mass spectrometry - Nitrogen compounds;
D O I
10.1515/znb-2002-0103
中图分类号
学科分类号
摘要
Isocyanic acid was prepared in pure form by reaction of KOCN or NaOCN with stearic or oxalic acid in good yield. Identification, characterization and investigation of the thermal stability of HNCO and evidence for a possible existence of dicyanic acid have been studied in gas phase, liquid and solid state by vibrational and NMR spectroscopy and mass spectrometry.
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页码:19 / 24
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