Preparation of nanometer-sized nickel powders by hydrothermal hydrogen reduction of Ni(OH)2 slurry

被引：0

作者：

Xu, Ju ^{[1
]}

Yu, Kening ^{[1
]}

Liang, Huanzhen ^{[1
]}

Tao, Changyuan ^{[1
]}

Li, Shaohua ^{[1
]}

Kim, Dongjin ^{[1
]}

Chung, Hunsaeng ^{[1
]}

机构：

[1] Inst. of Chem. Metall All., Chinese Acad. of Sci., Beijing 100080, China

来源：

Cailiao Yanjiu Xuebao/Chinese Journal of Materials Research | 2002年 / 16卷 / 02期

关键词：

Nickel compounds - Reduction;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The nickel powder samples obtained at different reaction steps of the hydrogen reduction of Ni(OH)2 slurries were examined by XRD, TEM, SEM and other methods. The obvious differences between samplings from acidic medium with pH12 were observed. The mechanism of hydrogen reduction of Ni(OH)2 slurry with pH2+ ions dissociated from basic nickel sulfates like Ni(SO4)0.3(OH)1.4 but for Ni(OH)2 slurry with pH>12 the mechanism was confirmed to be a heterogenous reaction of Ni(OH)2 solid particles and activated hydrogen occurred at the surface of Ni(OH)2.

引用

页码：158 / 163

共 50 条

[41] GRAIN-GROWTH OF PURE NICKEL AND OF A NI-SI SOLID-SOLUTION STUDIED BY DIFFERENTIAL SCANNING CALORIMETRY ON NANOMETER-SIZED CRYSTALS
KNAUTH, P
CHARAI, A
GAS, P
SCRIPTA METALLURGICA ET MATERIALIA, 1993, 28 (03): : 325 - 330
[42] Preparation of ceramics from magnetic-pulse-compacted nanometer-sized Al2O3 powder
Ivanov, VV
Khrustov, VR
INORGANIC MATERIALS, 1998, 34 (04) : 401 - 404
[43] Preparation of ultra-fine copper-nickel bimetallic powders with hydrothermal-reduction method
Wu, Songping
Ni, Jing
Jiao, Li
Zeng, Zhenou
MATERIALS CHEMISTRY AND PHYSICS, 2007, 105 (01) : 71 - 75
[44] Rates of ligand exchange between >FeIII-OH2 functional groups on a nanometer-sized aqueous cluster and bulk solution
Balogh, Edina
Todea, Ana Maria
MUller, Achim
Casey, William H.
INORGANIC CHEMISTRY, 2007, 46 (17) : 7087 - 7092
[45] Preparation and characterization of nanometer-sized magnetic photocatalyst TiO2/SiO2/Fe3O4
Liao, ZH
Chen, JJ
Yao, KF
Zhao, FH
Li, RX
JOURNAL OF INORGANIC MATERIALS, 2004, 19 (04) : 749 - 754
[46] Preparation and lithium ion storage performance of nano-sized β-Ni(OH)2
Li, Yanwei
Pan, Guanlin
Yao, Jinhuan
Li, Shiyu
Zhang, Lingzhi
Huagong Xuebao/CIESC Journal, 2015, 66 (12): : 5088 - 5095
[47] Preparation and Photocatalytic Properties of Nanometer-Sized Magnetic TiO2/SiO2/CoFe2O4 Composites
Li, Hansheng
Zhang, Yaping
Wu, Qin
Wang, Xitao
Liu, Changhao
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2011, 11 (11) : 10173 - 10181
[48] Self-reduction derived nickel nanoparticles in CdS/Ni(OH)2 heterostructure for enhanced photocatalytic hydrogen evolution
Wang, Xiaoning
Zhang, Xiaofei
Gao, Wenqiang
Sang, Yuanhua
Wang, Yanmin
Liu, Hong
JOURNAL OF CHEMICAL PHYSICS, 2020, 152 (21): : 214701
[49] Nanocrystalline Ni（OH）2 Preparation by Electrolysis in an Aqueous Solution of Nickel Nitrate
ZHANG Heng bin **
P. R. China
ChemicalResearchinChineseUniversities, 2002, (03) : 334 - 336
[50] Nanocrystalline Ni(OH)2 preparation by electrolysis in an aqueous solution of nickel nitrate
Zhang, HB
Li, XY
Cao, XJ
Li, SJ
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES, 2002, 18 (03) : 334 - 336

← 1 2 3 4 5 →