Advances in Primary Amine Synthesis by Reductive Amination of Alcohols Using Heterogeneous Metal Catalysts

被引：0

作者：

Liu Y.-X. ^{[1
]}

Shu H.-M. ^{[1
]}

Liu H.-Y. ^{[2
]}

Liu X.-S. ^{[1
]}

Zeng M. ^{[1
]}

Zhou K. ^{[1
]}

Wei Z.-J. ^{[2
]}

机构：

[1] Research and Development Base of Catalytic Hydrogenation, College of Pharmaceutical Science, Zhejiang University of Technology, Hangzhou

[2] Key Laboratory of Biomass Chemical Engineering of the Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou

来源：

Gao Xiao Hua Xue Gong Cheng Xue Bao/Journal of Chemical Engineering of Chinese Universities | 2018年 / 32卷 / 03期

关键词：

Alcohols; Heterogeneous catalyst; Primary amine; Reductive amination;

D O I：

10.3969/j.issn.1003-9015.2018.03.001

中图分类号：

学科分类号：

摘要：

Application of heterogeneous metal catalysts in the synthesis of primary amines via reductive amination of alcohols and NH3 is reviewed. Reaction mechanism of alcohol amination (including condensation amination and reductive amination) and catalytic systems used for reductive amination are summarized. Alcohol dehydrogenation is the rate-limiting step in reductive amination of alcohols and NH3. In addition, metal dehydrogenation activity varies due to their different adsorption capacities for NH3 and amines. Furthermore, this review gives an overview of primary amine synthesis, including the development of heterogeneous catalysts for reductive amination of alcohols and NH3 by hydrogen-autotransfer amination without hydrogen, employment of suitable supports and synthesis technology of primary amine compounds from biomass-based alcohols. © 2018, Editorial Board of "Journal of Chemical Engineering of Chinese Universities". All right reserved.

引用

页码：487 / 498

页数：11

共 71 条

[51] Shimizu K., Kanno S., Kon K., Et al., N-alkylation of ammonia and amines with alcohols catalyzed by Ni-loaded CaSiO<sub>3</sub> , Catalysis Today, 232, pp. 134-138, (2014)
[52] Sewell G.S., O'Connor C.T., Steen E.V., Effect of activation procedure and support on the reductive amination of ethanol using supported cobalt catalysts, Journal of Catalysis, 167, 2, pp. 513-521, (1997)
[53] Zamlynny V., Kubelkova L., Baburek E., Et al., Amination of cyclohexanol over metallosilicate-based materials, Applied Catalysis A: General, 169, 1, pp. 119-125, (1998)
[54] Fischer A., Maciejewski M., Burgi T., Et al., Cobalt-catalyzed amination of 1, 3-propanediol: effects of catalyst promotion and use of supercritical ammonia as solvent and reactant, Journal of Catalysis, 183, 2, pp. 373-383, (1999)
[55] Fischer A., Mallat T., Baiker A., Synthesis of 1, 4-diaminocyclohexane in supercritical ammonia, Journal of Catalysis, 182, 2, pp. 289-291, (1999)
[56] Fischer A., Mallat T., Baiker A., Continuous amination of propanediols in supercritical ammonia, Angewandte Chemie International Edition, 38, 3, pp. 351-354, (1999)
[57] Fischer A., Mallat T., Baiker A., Nickel-catalyzed amination of 1, 3-propanediols differently substituted at C2-position: influence of reactant structure on diamine production, Journal of Molecular Catalysis A: Chemical, 149, 1-2, pp. 197-204, (1999)
[58] Jenzer G., Mallat T., Baiker A., Cobalt-catalyzed amination of 1, 3-cyclohexanediol and 2, 4-pentanediol in supercritical ammonia, Catalysis Letters, 61, 3-4, pp. 111-114, (1999)
[59] Becker J., Niederer J.P.M., Keller M., Et al., Amination of cyclohexanone and cyclohexanol/cyclohexanone in the presence of ammonia and hydrogen using copper or a group VIII metal supported on a carrier as the catalyst, Applied Catalysis A: General, 197, 2, pp. 229-238, (2000)
[60] Chary K.V.R., Seela K.K., Naresh D., Et al., Characterization and reductive amination of cyclohexanol and cyclohexanone over Cu/ZrO<sub>2</sub> catalysts, Catalysis Communications, 9, 1, pp. 75-81, (2008)

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