Preparation and application of environment-friendly flame-retardant silicone-acrylic flocking adhesive

被引：0
|
作者：
Wu H. [1 ,2 ]
Jiang X. [1 ,2 ]
Cai Z. [1 ,2 ]
机构：
[1] College of Chemistry, Chemical Engineering & Biotechnology, Donghua University, Shanghai
[2] Key Laboratory of Science & Technology of Eco-Textile, Ministry of Education, Donghua University, Shanghai
来源：
Fangzhi Xuebao/Journal of Textile Research | 2018年 / 39卷 / 06期
关键词：
Acrylate; Adhesive; Alkylphenol ethoxylates; Ammonium polyphosphate; Electrostatic flocking; Environment-friendly; Flame-retardant;
D O I：
10.13475/j.fzxb.20170802805
中图分类号：
学科分类号：
摘要：
In order to develop high-added value and environment-friendly flocking adhesives, a flocking adhesive featured low-temperature curing, no formaldehyde releasing, alkylphenol ethoxylates (APEO) and flame-retardancy was synthesized by blending an organic and inorganic compound retardant in semi-continuous emulsion polymerization using ethyl acrylate, butyl acrylate, methyl methacrylate and acrylic acid as polymer monomers. The influence of different retardants, mass ratio of retardants, retardant amount, synergist amount on the flocking were investigated. The results show that flocking adhesive (FR) with 30% retardant (mass ratio of ammonium polyphosphate and FR-5 is 3:1) and 10% organic montmorillonite has good properties with flocking fastness, hand feeling and flame-retardancy. Copyright No content may be reproduced or abridged without authorization.
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页码：96 / 100
页数：4
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共 12 条
  • [1] Pi P., Wang W., Wen X., Et al., Synthesis and characterization of low-temperature self-crosslinkable acrylic emulsion for PE film ink, Progress in Organic Coatings, 81, 4, pp. 66-71, (2015)
  • [2] Pi P., Chen X., Wen X., Et al., Preparation and characterization of ambient-temperature self-crosslinkable water-soluble acrylic resin for PE film ink, Journals of Coatings Technology & Research, 13, 1, pp. 73-80, (2016)
  • [3] Li M., Lin X.S., Li X.Y., Et al., Preparation and property study of core-shell ambient-temperature crosslinkable polyacrylate binder, Applied Mechanics and Materials, 469, 11, pp. 3-6, (2013)
  • [4] Koukiotis C., Sideridou I.D., Preparation of high solids stable translucent nanolatexes of MMA/BA copolymers and MMA/BA/Veova-10 terpolymers with low MFFT using green industrial surfactants, Progress in Organic Coatings, 63, 1, pp. 116-122, (2008)
  • [5] Feng Y., Yuan J., Wang W., Et al., Synthesis and properties of waterborne polyacrylate coating dyeing binder, Journal of Textile Research, 38, 4, pp. 90-96, (2017)
  • [6] Di J., Liu Y., Ji F., Synthesis and properties of crosslinked polyurethane acrylate modified with organic silicon, Journal of Textile Research, 37, 1, pp. 75-80, (2016)
  • [7] Tan C., Tirri T., Wilen C.E., The effect of core-shell particle morphology on adhesive properties of poly (styrene-co-butyl acrylate), International Journal of Adhesion and Adhesives, 66, 4, pp. 104-113, (2016)
  • [8] Bai L., Huan S., Zhang X., Et al., Fabrication and evaluation of one-component core/shell structured latex adhesives containing poly (styrene) cores and poly (acrylate) shells, International Journal of Adhesion and Adhesives, 70, 10, pp. 152-159, (2016)
  • [9] Sui Z., Yang K., Chen J., Et al., Properties and application of fluorine-containing acrylate copolymer emulsion as finishing agent, Journal of Textile Research, 37, 9, pp. 100-105, (2016)
  • [10] Zong C., Guo L., Lu W., Research on ultrathin expansive type silicone-acrylic emulsion fire-retardant coatings, China Coatings, 31, 4, pp. 58-61, (2016)
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