Effects of novel energetic material NOG2Tz on thermal decomposition behavior of HMX

被引：0
|
作者：
Wang, Yang [1 ]
Qiu, Rui [1 ]
Wang, Qi [1 ]
Wang, En-Yu [1 ]
Zhao, Lin-Man [1 ]
Wang, Peng [1 ]
Chen, Fu-Xue [1 ]
Huang, Jing-Lun [2 ]
机构：
[1] School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, China
[2] Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621900, China
来源：
Hanneng Cailiao/Chinese Journal of Energetic Materials | 2014年 / 22卷 / 01期
关键词：
Apparent activation energy - Compatibility - Critical temperatures - Decomposition temperature - Exothermic decomposition - Organic Chemistry - Thermal behaviors - Thermal decomposition behavior;
D O I：
10.3969/j.issn.1006-9941.2014.01.005
中图分类号：
学科分类号：
摘要：
The decomposition temperatures of composite explosives (HMX+NOG2Tz) in different mass proportions were measured by differential scanning calorimetry (DSC). The detonation velocities of composite explosives were calculated by an empirical equation. The thermal behavior of the composite explosive 9# (80%HMX+20% NOG2Tz) was studied by DSC at different heating rates. The apparent activation energy and pre-exponential factor of the exothermic decomposition reaction, the temperature (Te0) of the extrapolated onset in heating rate β→0, and the critical temperature of thermal explosion (Tb) were calculated. The results show that the decomposition peak temperature of the composite explosive 9# increases by 2°C and the apparent activation energy by 70 kJ·mol-1over the pure HMX. It indicates that the addition of NOG2Tz (
引用
收藏
页码：22 / 25
相关论文
共 50 条
  • [31] Study on effect of heating rate on thermal decomposition of HMX energetic materials by In-Situ diffuse reflection FUR spectrum
    Liu Xue-yong
    Wang Lin
    Zheng Min-xia
    Jiang Yan
    Luo Yi-wei
    SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27 (10) : 1951 - 1954
  • [32] THERMAL-DECOMPOSITION OF ENERGETIC MATERIALS .52. ON THE FOAM ZONE AND SURFACE-CHEMISTRY OF RAPIDLY DECOMPOSING HMX
    PALOPOLI, SF
    BRILL, TB
    COMBUSTION AND FLAME, 1991, 87 (01) : 45 - 60
  • [33] Study on effect of heating rate on thermal decomposition of HMX energetic materials by in-situ diffuse reflection FTIR spectrum
    Liu, Xue-Yong
    Wang, Lin
    Zheng, Min-Xia
    Jiang, Yan
    Luo, Yi-Wei
    Guang Pu Xue Yu Guang Pu Fen Xi/Spectroscopy and Spectral Analysis, 2007, 27 (10): : 1951 - 1954
  • [34] Evaluating the Effect of Nanosized CoCuFe2O4 for Thermal Decomposition of Nitrotriazolone High Energetic Material
    Dave, Pragnesh N.
    Sirach, Ruksana
    Deshpande, Milind P.
    CHEMISTRYSELECT, 2022, 7 (32):
  • [35] Structural Characterization and Thermal Behavior of a Novel Energetic Material: 1-Amino-1-(2,4-dinitrophenylhydrazinyl)-2,2-dinitroethylene
    Ren, Xiaolei
    Zuo, Xiangang
    Xu, Kangzhen
    Ren, Yinghui
    Huang, Jie
    Song, Jirong
    Wang, Bozhou
    Zhao, Fengqi
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2011, 32 (07): : 2267 - 2273
  • [36] CFD Cook-Off Simulation and Thermal Decomposition of Confined High Energetic Material
    Asante, Daniel O.
    Kim, Shinhyuk
    Chae, Jooseung
    Kim, Hyounsoo
    Oh, Min
    PROPELLANTS EXPLOSIVES PYROTECHNICS, 2015, 40 (05) : 699 - 705
  • [37] Synergistic Catalytic Effect of a Series of Energetic Coordination Compounds based on Tetrazole-1-acetic Acid on Thermal Decomposition of HMX
    Qu, Yuan-Yuan
    Wei, Zhi-Xian
    Kang, Li
    Xie, Fei
    Zhang, He-Dan
    Yue, Pan
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2017, 643 (12): : 742 - 748
  • [38] Catalytic effects of nano additives on decomposition and combustion of RDX-, HMX-, and AP-based energetic compositions
    Yan, Qi-Long
    Zhao, Feng-Qi
    Kuo, Kenneth K.
    Zhang, Xiao-Hong
    Zeman, Svatopluk
    DeLuca, Luigi T.
    PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2016, 57 : 75 - 136
  • [39] Novel energetic coordination compound [Cu(AT)4]Cl2 for catalytic thermal decomposition of ammonium perchlorate
    Huang, Tao
    Hao, Wenjia
    Jin, Bo
    Zhang, Jinhao
    Guo, Jinkun
    Luo, Liqiong
    Zhang, Qingchun
    Peng, Rufang
    JOURNAL OF SOLID STATE CHEMISTRY, 2021, 304
  • [40] Thermal and combustion behavior of novel oxygen-rich energetic pyrazoles
    Serushkin, Valery V.
    Sinditskii, Valery P.
    Hoang, Trung H.
    Filatov, Sergey A.
    Shipulina, Anna S.
    Dalinger, Igor L.
    Shakhnes, Aleksander Kh
    Sheremetev, Aleksey B.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2018, 132 (01) : 127 - 142
12345