New Analytical Strategy for Bioaccessibility Evaluation of Bromine and Iodine from Edible Seaweeds

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作者
Scaglioni, Priscila T. [1 ]
Balbinot, Fernanda P. [1 ]
Rondan, Filipe S. [1 ]
Novo, Diogo L. R. [1 ]
Silva, Alisson A. [1 ]
Mesko, Marcia F. [1 ]
机构
[1] Centro de Ciências Químicas, Farmacêuticas e de Alimentos, Universidade Federal de Pelotas, RS, Capão do Leão,96160-000, Brazil
关键词
Bromine - Combustion - Degradation - Iodine - Microwave integrated circuits - Seaweed - Secondary ion mass spectrometry;
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摘要
A strategy for determining the bioaccessibility of bromine and iodine from edible seaweeds was proposed for the first time using microwave-induced combustion (MIC) and ion chromatography coupled to mass spectrometry (IC-MS) after in vitro digestion. The concentrations of bromine and iodine in edible seaweeds using the proposed methods (MIC and IC-MS) were not statistically different from those using MIC and inductively coupled plasma mass spectrometry (p > 0.05). Trueness was assessed by recovery experiments (101-110%, relative standard deviation 0.05) was observed between the total concentration of bromine or iodine and their concentration in bioaccessible and residual fractions for three edible seaweed species, indicating full analyte quantification in the fractions. © 2023 American Chemical Society.
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