Hierarchical porous ZnMn2O4 microsphere anode

被引：0

作者：

Ren Y. ^{[1
]}

Zhang S. ^{[2
]}

Zhang L. ^{[1
]}

He X. ^{[3
]}

Zhao J. ^{[4
]}

机构：

[1] College of Chemistry Chemical Engineering and Material Science, Zaozhuang University, Zaozhuang

[2] School of Materials Science and Engineering, Beihang University, Beijing

[3] State Key Laboratory for Superlattices and Microstructures, Institute of Semiconductors, Chinese Academy of Sciences, Beijing

[4] State Grid Henan Electric Power Company, Zhengzhou

来源：

Beijing Hangkong Hangtian Daxue Xuebao/Journal of Beijing University of Aeronautics and Astronautics | 2020年 / 46卷 / 02期

基金：

中国博士后科学基金;

关键词：

Anode; Hierarchical porous microsphere; Hydrothermal synthesis; Lithium ion batteries; ZnMn[!sub]2[!/sub]O[!sub]4[!/sub;

D O I：

10.13700/j.bh.1001-5965.2019.0190

中图分类号：

学科分类号：

摘要：

The precursor of Zn-Mn oxides were synthesized by a facile hydrothermal method and subsequently calcined at different temperature of 400℃, 500℃, 600℃ and 700℃ in air in order to synthesis the hierarchical porous ZnMn2O4 microspheres assembled by a lot of nanosheets. The ZnMn2O4 microspheres synthesized by calcining precursor in air at 500℃ (ZMO-500) display rich hierarchical porous structures, and when used as the anode material of lithium ion batteries, ZMO-500 microsphere anode material exhibits a high discharge capacity of 1 132 mAh/g after 500 cycles at a current density of 500 mA/g. It is believed that the outstanding electrochemical performance of ZMO-500 microsphere anode material benefits from the hierarchical porous structure that can not only increase the contact area between the electrode and the electrolyte to facilitate the transfer of Li+, but also provide sufficient space for volume expansion of the electrode during the cyclic process. © 2020, Editorial Board of JBUAA. All right reserved.

引用

页码：259 / 265

页数：6

共 22 条

[21] Liu X., Zhang S., Xing Y., Et al., MOF-derived, N-doped porous carbon coated graphene sheets as high-performance anodes for lithium-ion batteries, New Journal of Chemistry, 40, 11, pp. 9679-9683, (2016)
[22] Sun H., Xin G., Hu T., Et al., High-rate lithiation-induced reactivation of mesoporous hollow spheres for long-lived lithium-ion batteries, Nature Communication, 31, 5, pp. 4526-4529, (2014)

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