Photomechanical Crystals as Light-Activated Organic Soft Microrobots

被引:5
|
作者
Tahir, Ibrahim [1 ]
Ahmed, Ejaz [2 ]
Karothu, Durga Prasad [1 ]
Fsehaye, Filmon [2 ]
Halabi, Jad Mahmoud [2 ]
Naumov, Pance [1 ,3 ,4 ]
机构
[1] New York Univ Abu Dhabi, Ctr Smart Engn Mat, Abu Dhabi 129188, U Arab Emirates
[2] New York Univ Abu Dhabi, Smart Mat Lab, Abu Dhabi 129188, U Arab Emirates
[3] Macedonian Acad Sci Arts, Res Ctr Environm Mat, Skopje 1000, North Macedonia
[4] NYU, Mol Design Inst, Dept Chem, New York, NY 10003 USA
关键词
MOLECULAR-CRYSTALS; SINGLE-CRYSTALS; MACROSCOPIC STRAIN; MECHANICAL MOTION; SHAPE CHANGES; DIARYLETHENE;
D O I
10.1021/jacs.4c08320
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the field of materials science, dynamic molecular crystals have attracted significant attention as a novel class of energy-transducing materials. However, their development into becoming fully functional actuators remains somewhat limited. This study focuses on one family of dynamic crystalline materials and delves into exploring the efficiency of conversion of light energy to mechanical work. A simple setup is designed to determine a set of performance indices of anthracene-based crystals as an exemplary class of dynamic molecular crystals. The ability of these crystals to reversibly bend due to dimerization is realistically assessed from the perspective of the envisaged soft robotics applications, where wireless photomechanical grippers manipulate and assemble microscopic objects driven and controlled by light instead of lines and motors. The approach described here not only guides the quantification of responsive molecular crystals' actuation potential but also aims to attract an interdisciplinary interest to further develop this class of materials into controllable all-organic actuating elements to be used in microrobotics for engineering or biomedicine.
引用
收藏
页码:30174 / 30182
页数:9
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