Preparation of hydrophilic woven fabrics: Surface modification of poly(ethylene terephthalate) by grafting of poly(vinyl alcohol) and poly(vinyl alcohol)-g-(N-vinyl-2-pyrrolidone)

被引：0
|
作者：
Erdoğan, Meryem Kalkan [1 ]
Akdemir, Özgür [2 ]
Hamitbeyli, Agamirza [2 ]
Karakışla, Meral [1 ]
机构：
[1] Department of Chemistry, Faculty of Science, Ankara University, 06100 Tandoğan, Ankara, Turkey
[2] SANKO Textile Enterprises Co., ISKO Woven Firm, Organized Industrial Zone, 3. Street, Inegol, Bursa,16400, Turkey
来源：
Journal of Applied Polymer Science | 2020年 / 137卷 / 16期
关键词：
One of the most industrially important synthetic textile materials; woven poly(ethylene terephthalate) (PET) fabrics; have limitations in the usage of casual apparel applications due to their unwanted hydrophobicity. For that reason; in this study; to impart permanent hydrophilicity to the PET fabrics; hydrophilic poly(vinyl alcohol) (PVA) and a PVA-based copolymer were introduced to the alkaline hydrolysis pretreated PET surface by graft copolymerization for the first time. The graft modification of PET fabric surface was performed with an industrial-adaptable approach. The synthesis of a novel PVA-g-(N-vinyl-2-pyrrolidone) copolymer was achieved by the introduction of glycidyl methacrylate monomer to the PVA backbone. The structure of the copolymer was evidenced by attenuated total reflection–Fourier transform infrared spectroscopy and 1H-NMR techniques. The introduction of PVA and copolymer structures with desired functional groups to the PET fabric surface was confirmed with the X-ray photoelectron spectroscopy technique. It was obtained that the contact angle–wetting time of PET fabric (145° and 98 s) could be dropped to 37° and 0.1 s and 64° and 0.7 s after PVA and copolymer grafting; respectively. This suggests that the graft-modified PET fabrics may find the potential of use in the textile applications as the alternative hydrophilic materials. © 2019 Wiley Periodicals; Inc; J; Appl; Polym; Sci; 2020; 137; 48584. © 2019 Wiley Periodicals;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Journal article (JA)
引用
收藏
相关论文
共 50 条
  • [31] Preparation, characterization, electrical and antibacterial properties of sericin/poly(vinyl alcohol)/poly(vinyl pyrrolidone) composites
    Ramesan, M.T. (mtramesan@uoc.ac.in), 1600, John Wiley and Sons Inc (133):
  • [32] Preparation and Properties of Poly(vinyl alcohol)/Poly(vinyl pyrrolidone) Composites for Solid Alkaline Electrolyte Membranes
    Fu Jing
    Lin Rui
    Lue Hong
    Wang Xiao-Lei
    Ma Jian-Xin
    Qiao Jin-Li
    ACTA PHYSICO-CHIMICA SINICA, 2010, 26 (10) : 2653 - 2658
  • [33] Preparation and characterization of poly(vinyl alcohol)-poly(vinyl pyrrolidone) blend: A biomaterial with latent medical applications
    Bernal, Andres
    Kuritka, Ivo
    Saha, Petr
    JOURNAL OF APPLIED POLYMER SCIENCE, 2013, 127 (05) : 3560 - 3568
  • [34] Preparation and Characterization of Poly Vinyl Alcohol/Poly Vinyl Pyrrolidone/Clay Based Nanocomposite by Gamma Irradiation
    El-Arnaouty, M. B.
    Eid, M.
    Salah, M.
    Hegazy, El-Sayed A.
    JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2012, 49 (12): : 1041 - 1051
  • [35] Surface Modification of Poly(vinyl alcohol) Fibers
    Chirowodza, Helen
    Sanderson, Ronald D.
    MACROMOLECULAR MATERIALS AND ENGINEERING, 2010, 295 (11) : 1009 - 1016
  • [36] Preparation, characterization, electrical and antibacterial properties of sericin/poly(vinyl alcohol)/poly(vinyl pyrrolidone) composites
    Ramesan, M. T.
    Athira, V. K.
    Jayakrishnan, P.
    Gopinathan, C.
    JOURNAL OF APPLIED POLYMER SCIENCE, 2016, 133 (24)
  • [37] Surface modification of poly(vinyl alcohol) by peroxide-initiated grafting of a poly(organophosphazene)
    Pemberton, L
    DeJaeger, R
    CHEMISTRY OF MATERIALS, 1996, 8 (07) : 1391 - 1395
  • [38] MISCIBILITY OF POLY(N-VINYL-2-PYRROLIDONE) WITH A COPOLYAMIDE
    GUO, QP
    YU, M
    FENG, ZL
    POLYMER, 1992, 33 (04) : 893 - 895
  • [39] Preparation and characterization of cellulose/poly (N-vinyl-2-pyrrolidone hydrogels
    Fahmy, H. M.
    Montaser, A. S.
    EGYPTIAN JOURNAL OF CHEMISTRY, 2023, 66 (09): : 245 - 255
  • [40] An ultrasonic assisted process for the synthesis of poly(vinyl alcohol)-poly (N-vinyl-2-pyrrolidone) nanocomposites filled with modified nano-Zirconia
    Mallakpour, Shadpour
    Shafiee, Elaheh
    PROGRESS IN ORGANIC COATINGS, 2018, 121 : 120 - 129
12345