Bismuth- and Iron-Catalyzed Three-Component Synthesis of α-Amino Acid Derivatives: A Simple and Convenient Route to α-Arylglycines

被引：0

作者：

Halli J. ^{[1
]}

Schneider A.E. ^{[1
]}

Beisel T. ^{[1
]}

Kramer P. ^{[1
]}

Shemet A. ^{[1
]}

Manolikakes G. ^{[1
]}

机构：

[1] Department of Organic Chemistry and Chemical Biology, Goethe-University Frankfurt, Max-von-Laue-Straße 7, Frankfurt am Main

来源：

Synthesis (Germany) | 2017年 / 49卷 / 04期

关键词：

amino acids; aza-Friedel-Crafts reaction; bismuth; homogeneous catalysis; iron; multicomponent reactions;

D O I：

10.1055/s-0035-1561499

中图分类号：

学科分类号：

摘要：

Efficient bismuth- and iron-catalyzed three-component syntheses of α-arylglycines have been developed. These methods provide a general, atom-economic route to various N-protected α-arylglycines starting from readily available amides (or carbamates), glyoxalates, and (hetero)arenes with water as the only by-product. Scope and limitations of bismuth- and iron-catalyzed reactions are discussed and compared. In addition, mechanistic investigations as well as initial forays into stereoselective three-component reactions are presented. © Georg Thieme VerlagStuttgart · New York.

引用

页码：849 / 879

页数：30

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