Effect of water vapour on the high temperature oxidation of stainless steels

被引:9
|
作者
Chandra-Ambhorn S. [1 ]
Wongpromrat P. [2 ]
Thublaor T. [1 ]
Chandra-Ambhorn W. [2 ]
机构
[1] High Temperature Corrosion Research Centre, Department of Materials and Production Technology Engineering, Faculty of Engineering, King Mongkut’s University of Technology North Bangkok, 1518, Pracharat 1 Road, Bangsue, Bangkok
[2] Department of Chemical Engineering, Faculty of Engineering, King Mongkut’s Institute of Technology Ladkrabang, Chalongkrung 1 Road, Lat Krabang, Bangkok
关键词
Alloying element; Alumina; Chromia; High temperature oxidation; Stainless steel;
D O I
10.4028/www.scientific.net/SSP.300.107
中图分类号
学科分类号
摘要
This chapter primarily reviews the nature of water vapour when it presents in bulk gas. The change in a ratio between water vapour and corresponding dissociated hydrogen, which determine the thermodynamic stability of the oxide formation, is analysed when the oxidation kinetics are linear and parabolic. When water vapour reaches the solid/gas interface, chromium species volatilisation and oxidation controlled by surface reaction can occur. The adsorbed water vapour can be further incorporated into the oxide possibly in the form of hydrogen defects. The role of these defects on altering the defect structure of the oxide is discussed. Finally, characteristics of the oxide scale on stainless steels formed in the atmosphere containing water vapour are reviewed. © 2020 Trans Tech Publications Ltd, Switzerland.
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页码:107 / 134
页数:27
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