Mass-spectrometry study of gas-phase reactions of macrobicyclic iron(II) complexes

被引：0
|
作者：
Varzatskij, O.A. [1 ]
Tkachenko, E.Yu. [1 ]
Voloshin, Y.Z. [1 ]
Pokrovskij, V.A. [1 ]
Maletin, Y.A. [1 ]
机构：
[1] Inst. Obshchej i Neorgan. Khimii, Kiev, Ukraine
来源：
Ukrainskij Khimicheskij Zhurnal | 2002年 / 68卷 / 1-2期
关键词：
Glycerol - Ionization - Iron compounds - Mass spectrometry - Oligomers;
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学科分类号：
摘要：
In great numbers of FAB mass-spectrometry investigations of clathrochelate complexes using traditional matrices (glycerol and oligoethylene glycol), pseudomolecular ion was not observed. Matrices that make possible to get informative spectra of macrobicyclic iron(II) complexes of different types and various charge were found. The ionization and fragmentation mechanism is determined to be dependent on the structure of matrice.
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页码：76 / 83
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