Bacterial nanocellulose as green support of platinum nanoparticles for effective methanol oxidation

被引:6
|
作者
Ponjavic M. [1 ]
Stevanovic S. [1 ]
Nikodinovic-Runic J. [2 ]
Jeremic S. [2 ]
Cosovic V.R. [1 ]
Maksimovic V. [3 ]
机构
[1] University of Belgrade, Institute of Chemistry, Technology and Metallurgy, Njegoseva 12, Belgrade
[2] Institute of Molecular Genetics and Genetic Engineering, University of Belgrade, Vojvode Stepe 333a, Belgrade
[3] Vinca Institute of Nuclear Sciences, University of Belgrade, National Institute of the Republic of Serbia, Mike Petrovića Alasa 12-14, Belgrade
基金
欧盟地平线“2020”;
关键词
Bacterial nanocellulose; Green support; Methanol oxidation; Microwave synthesis; Pt catalyst;
D O I
10.1016/j.ijbiomac.2022.10.278
中图分类号
学科分类号
摘要
Bacterial nanocellulose, BNC, has emerged as a new class of nanomaterials recognized as renewable, biodegradable, biocompatible and material for versatile applications. BNC also proved as a perfect support matrix for metallic nanoparticle synthesis and appeared as suitable alternative for widely used carbon based materials. Following the idea to replace commonly used carbon based materials for platinum supports with the green and sustainable one, BNC appeared as an excellent candidate. Herein, microwave assisted synthesis has been reported for the first time for platinum nanoparticles supported on BNC as green material. Bacterial nanocelullose-platinum catalyst, Pt/BNC, was investigated by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), atomic force microscopy (AFM), X-ray diffractometry (XRD) and transmission-electron microscopy (TEM) analysis. The obtained results confirmed successful synthesis of new Pt-based catalyst. It was found that Pt/BNC catalyst has high electrocatalytic performance in methanol oxidation reaction. Green/sustainable catalytic system is highly desirable and provided by the elegant microwave assisted synthesis of Pt/BNC will pave the way for a larger scale application and expedite the market penetration of such fuel cells. © 2022 Elsevier B.V.
引用
收藏
页码:1474 / 1484
页数:10
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