Influence of La3+ doping on structural and optical properties of SrCeO3 perovskite

被引:0
|
作者
Yadav, Dharmendra [1 ]
Kumar, Pravin [2 ]
Tripathi, Alok Kumar [3 ]
Yadav, Ram Sagar [4 ]
Nirala, Gurudeo [5 ]
Yadav, Sushma [6 ]
Yadav, Ashish Kumar [7 ]
Yadav, Sandip [8 ]
机构
[1] SKM Univ Dumka Jharkhand, Model Coll Deoghar, Dept Phys, Dumka, India
[2] Banaras Hindu Univ, Inst Sci, Dept Chem, Varanasi 221005, Uttar Pradesh, India
[3] Univ Delhi, Ramjas Coll, Dept Phys, Delhi 110007, India
[4] Banaras Hindu Univ, Inst Sci, Varanasi 221005, Uttar Pradesh, India
[5] Govt Polytech Munger, Dept Basic Sci & Humanities, Munger 811213, India
[6] Govt Polytech Bakshi Ka Talab, Dept Mech Engn, Lucknow 226201, Uttar Pradesh, India
[7] Univ Mumbai, RJ Coll, Mumbai, Maharashtra, India
[8] Univ Allahabad, Dept Phys, Allahabad 221005, Uttar Pradesh, India
关键词
SrCeO3; XRD; TEM; Raman; FTIR; UV-visible spectroscopy; PURE;
D O I
10.1088/1402-4896/ad804c
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The SrCe1-xLaxO3 (x = 0.0, 0.02, 0.4, 0.6, and 0.10) perovskite materials have been successfully synthesized by auto-combustion method and calcined at 1100 degrees C. The XRD patterns reveal a highly crystalline orthorhombic crystal structure with a Pnma space group in all samples. The TEM micrograph shows a spherical morphology of the 10 mol% La3+ doped SrCeO3 perovskite sample alongwith the SAED pattern confirming its highly crystalline nature. The incorporation of La3+ ion in the SrCeO3 perovskite has been confirmed by the Raman and Fourier transform infrared (FTIR) measurements. The UV-vis absorption spectra at room temperature show various bands, with a strong absorption band observed below 400 nm. The optical band gap of the undoped and La3+ doped samples have been calculated and it is smaller for the La3+ doped perovskite samples than that of the undoped perovskite sample. Therefore, the La3+ doped SrCeO3 perovskite may be applicable for optoelectronic applications.
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页数:9
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