Particle size - Synthesis (chemical) - Infrared devices - Emission spectroscopy - High resolution transmission electron microscopy - Calcination - Particle size analysis - Barium compounds - Fluorescence - Solid state reactions - Tin compounds - X ray diffraction;
D O I:
10.3788/fgxb20133401.0018
中图分类号:
学科分类号:
摘要:
BaSnO3 nano-phosphors were prepared by solvothermal method using glycol-water mixed solution as a solvent, followed by calcinations at different temperature. The as-synthesized samples were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), the nano-particle size analyzer, UV-Vis-NIR spectrophotometer, excitation and emission spectra. The nano-powders are sphere with sizes of 30~50 nm. Good dispersity can be achieved even after the sample was calcined. Efficient near-infrared fluorescence with emission peak of 895 nm was observed under the excitation of 385 nm. Comparing with the sample prepared by solid state reaction, the emission intensities increase about ten folds. The degree of crystallization is found to be the main fact of the near-infrared fluorescence of BaSnO3 nanoparticles.
机构:
RIKEN Ctr Sustainable Resource Sci, Mol Struct Characterizat Unit, 2-1 Hirosawa, Wako, Saitama 3510198, JapanUniv Tokyo, Grad Sch Pharmaceut Sci, 7-3-1 Hongo,Bunkyo ku, Tokyo 1130033, Japan
机构:
Univ Texas Hlth Sci Ctr Houston, Houston, TX 77030 USA
St Lukes Hosp, The Woodlands, TX USA
Mem Herman Hosp, Houston, TX USAUniv Texas Hlth Sci Ctr Houston, Houston, TX 77030 USA