Recent progress on photoactive nonprecious transition-metal complexes

被引：0

作者：

ZhongLiang Gong ^{[1
]}

HongJie Zhang ^{[2
]}

Yan Cheng ^{[3
]}

Jianxun Liu ^{[4
]}

Yuhan Ai ^{[5
]}

Yaqin Li ^{[6
]}

Zhihui Feng ^{[6
]}

Qiong Zhang ^{[6
]}

Shaolong Gong ^{[5
]}

Yong Chen ^{[7
]}

ChangJiang Yao ^{[4
]}

YuanYuan Zhu ^{[3
]}

LiangJin Xu ^{[2
]}

YuWu Zhong ^{[1
]}

机构：

[1] CAS Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences

[2] State Key Laboratory of Structural Cemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences

[3] School of Chemistry and Chemical Engineering, Anhui Key Laboratory of Advanced Catalytic Materials and Reaction Engineering,Hefei University of Technology

[4] State Key Laboratory of Explosion Science and Safety Protection, School of Mechatronical Engineering, Beijing Institute of Technology

[5] College of Chemistry and Molecular Sciences, Hubei Key Lab on Organic and Polymeric Optoelectronic Materials, Wuhan University

[6] School of Chemistry and Chemical Engineering, Anhui University

[7] Key Laboratory of Photochemical Conversion and Optoelectronic Materials & CAS-HKU Joint Laboratory on New Materials, Technical Institute of Physics and Chemistry, Chinese Academy of

来源：

Science China(Chemistry) | 2025年 / 68卷 / 01期

关键词：

D O I：

暂无

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

摘要：

Photoactive complexes of nonprecious transition metals, mainly including those in the first-row and partially the second-row of the Periodic table of elements, have received increasing attention in view of their low cost and long-term sustainability. They are recognized as promising alternatives to noble transition metal complex congeners that have been extensively studied in optoelectronic devices, artificial photosynthesis, photocatalysis, biodiagnostics, and therapeutics, etc. This review is devoted to a comprehensive summary on the classical and recent advances on photoactive nonprecious transition metal complexes, including photoactive Zr, V, Cr, Mo, and W complexes, Mn complexes and hybrids, Fe, Co, Ni, and Cu complexes, and Zn and Cd complexes and hybrids. A particular focus is given on the molecular design, modulation of photophysical and photochemical properties, and applications of the representative and lately-developed nonprecious metal complexes. In addition, a perspective on the future development in this field is provided at the end of this review.

引用

页码：46 / 95

页数：50

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