Photocatalytic fluorosulfonylation of aliphatic carboxylic acid NHPI esters

被引：0

作者：

Zhang, Honghai ^{[1
]}

Li, Shaojie ^{[1
]}

Zheng, Han-Liang ^{[2
]}

Zhu, Gangguo ^{[2
]}

Liao, Saihu ^{[1
,3
]}

Nie, Xingliang ^{[1
,2
]}

机构：

[1] Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou,350108, China

[2] Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Department of Chemistry, Zhejiang Normal University, 688 Yingbin Road, Jinhua,321004, China

[3] Beijing National Laboratory of Molecular Science (BNLMS), Beijing,100190, China

来源：

Organic Chemistry Frontiers | 2022年 / 9卷 / 18期

基金：

中国国家自然科学基金;

关键词：

Carboxylic acids - Esters - Fluorine compounds;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Sulfonyl fluorides have been increasingly favored by medicinal chemists and chemical biologists because of their unique reactivity and stability, but their synthetic methods still have certain limitations. Based on the SO2 radical insertion/fluorination strategy, we have developed a novel method for photocatalytic induced synthesis of alkylsulfonyl fluorides (low to 1 mol% P.C. and up to 92% yield), which covers primary, secondary and tertiary aliphatic carboxylic acid NHPI esters, providing a facile method for the late-stage fluorosulfonylation of natural products and drugs. This method provides an efficient and reliable approach for the synthesis and application of alkylsulfonyl fluorides. © 2022 The Royal Society of Chemistry.

引用

页码：4854 / 4860

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