Liquid-Liquid Extraction of Formic Acid with 2-Methyltetrahydrofuran: Experiments, Process Modeling, and Economics

被引：0

作者：

Laitinen, Antero T. ^{[1
]}

Parsana, Vyomesh M. ^{[2
]}

Jauhiainen, Olli ^{[1
]}

Huotari, Marco ^{[1
]}

Van Den Broeke, Leo J. P. ^{[3
]}

De Jong, Wiebren ^{[4
]}

Vlugt, Thijs J. H. ^{[3
]}

Ramdin, Mahinder ^{[3
]}

机构：

[1] Vtt Technical Research Centre of Finland, Tietotie 4 E, Espoo,FI-02044, Finland

[2] Department of Chemical Engineering, V.V.P. Engineering College, Gujarat Technological University, Rajkot, Gujarat,360005, India

[3] Engineering Thermodynamics, Process and Energy Department, Faculty of Mechanical, Maritime and Materials Engineering, Delft University of Technology, Leeghwaterstraat 39, Delft,2628CB, Netherlands

[4] Large-Scale Energy Storage, Process and Energy Department, Faculty of Mechanical, Maritime and Materials Engineering, Delft University of Technology, Leeghwaterstraat 39, Delft,2628CB, Netherlands

来源：

Industrial and Engineering Chemistry Research | 2021年 / 60卷 / 15期

关键词：

Liquids - Supercritical fluid extraction - Carbon dioxide - Carbon monoxide - Distillation - Economic analysis - Product design - Cost effectiveness - Electrolytic reduction;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Formic acid (FA) is an interesting hydrogen (H2) and carbon monoxide (CO) carrier that can be produced by the electrochemical reduction of carbon dioxide (CO2) using renewable energy. The separation of FA from water is challenging due to the strong (cross)association of the components and the presence of a high boiling azeotrope. For the separation of dilute FA solutions, liquid-liquid extraction is preferred over conventional distillation because distilling large amounts of water is very energy-intensive. In this study, we use 2-methyltetrahydrofuran (2-MTHF) to extract FA from the CO2 electrolysis process, which typically contains ©

引用

页码：5588 / 5599

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