Simulation and verification of hydrogen production by diesel reforming in a palladium membrane reactor

被引：0
|
作者：
Mi W.-L. [1 ,2 ]
Zhang N. [2 ]
Zou Z.-W. [2 ]
机构：
[1] Sinopec Research Institute of Petroleum Processing, Beijing
[2] Department of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing
来源：
Gao Xiao Hua Xue Gong Cheng Xue Bao/Journal of Chemical Engineering of Chinese Universities | 2019年 / 33卷 / 05期
关键词：
Diesel reforming; Hydrogen production; Palladium membrane reactor; Sensitivity analysis;
D O I：
10.3969/j.issn.1003-9015.2019.05.012
中图分类号：
学科分类号：
摘要：
In order to study the reaction mechanism of hydrogen production by diesel reforming in palladium membrane reactors, thermodynamics and kinetics of the reaction process were modeled, and the accuracy of the model was verified by experiments. Palladium membrane reactors were classified as continuous sub-reactors and sub-separators by sequential module to simulate the reaction separation coupling process. Effects of various reaction factors on hydrogen yield were studied through sensitivity analysis. The results show that compared with the membraneless reactors, the palladium membrane reactor can overcome thermodynamic equilibrium limits, reduce reaction volume and obtain higher hydrogen yield at lower temperatures. The deviation between the simulation results and the experimental values is 8.9%, which proves that the simulation model can predict and guide experimental research. © 2019, Editorial Board of "Journal of Chemical Engineering of Chinese Universities". All right reserved.
引用
收藏
页码：1113 / 1122
页数：9
相关论文
共 30 条
  • [11] Tosti S., Basile A., Borelli R., Et al., Ethanol steam reforming kinetics of a Pd-Ag membrane reactor, International Journal of Hydrogen Energy, 34, 11, pp. 4747-4754, (2009)
  • [12] Jin Y., Rui Z.B., Tian Y., Et al., Sequential simulation of dense oxygen permeation membrane reactor for hydrogen production from oxidative steam reforming of ethanol with ASPEN PLUS, International Journal of Hydrogen Energy, 35, 13, pp. 6691-6698, (2010)
  • [13] Feng D.M., Wang Y.Y., Wang D.Z., Et al., Hydrogen permeation performance of a Pd-Ag membrane reactor in dimethyl ether steam reforming system, Journal of Chemical Engineering of Chinese Universities, 24, 1, pp. 58-63, (2010)
  • [14] Chen Y.Z., Xu H.Y., Wang Y.Z., Et al., Hydrogen production from the steam reforming of liquid hydrocarbons in membrane reactor, Catalysis Today, 118, 1-2, pp. 136-144, (2006)
  • [15] Miyamoto M., Hayakawa C., Kamata K., Et al., Influence of the prereformer in steam reforming of dodecane using a Pd alloy membrane reactor, International Journal of Hydrogen Energy, 36, 13, pp. 7771-7775, (2011)
  • [16] Kirillov V.A., Shigarov A.B., Amosov Y.I., Et al., Production of pure hydrogen from diesel fuel by steam prereforming and subsequent conversion in a membrane reactor, Petroleum Chemistry, 58, 2, pp. 103-113, (2018)
  • [17] Kang I., Bae J., Bae G., Performance comparison of autothermal reforming for liquid hydrocarbons, gasoline and diesel for fuel cell applications, Journal of Power Sources, 163, 1, pp. 538-546, (2006)
  • [18] Sabio E., Murillo A.A., Gonzalez J.F., Et al., Modelling the composition of the gas obtained by steam reforming of glycerine, Energy Conversion and Management, 146, 15, pp. 147-157, (2017)
  • [19] Senseni A.Z., Rezaei M., Meshkani F., Glycerol steam reforming over noble metal nanocatalysts, Chemical Engineering Research and Design, 123, pp. 360-366, (2017)
  • [20] Xu L.H., Mi W.L., Su Q.Q., Influence of inlet gas components on the diesel steam reforming of proton exchange membrane fuel cells for hydrogen production, Journal of University of Science and Technology Beijing, 34, 6, pp. 75-84, (2012)
123