Amplification Methods of Nitrogen Chains in the Synthesis of Energetic Materials

被引：0
|
作者：
Zhu Y. [1 ]
Ding K.-W. [1 ,2 ]
Xiao C. [3 ]
Li T.-Q. [1 ]
Bu J.-H. [1 ]
Liu W. [1 ]
Guo S.-S. [1 ]
Ge Z.-X. [1 ,2 ]
机构：
[1] Xi'an Modern Chemistry Research Institute, Xi'an
[2] State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an
[3] Academy of Chinese Weapon Science, Beijing
来源：
Huozhayao Xuebao/Chinese Journal of Explosives and Propellants | 2021年 / 44卷 / 01期
关键词：
All-nitrogen material; Amplification method of nitrogen chain; N10; N11; N5; N8; Organic chemistry;
D O I：
10.14077/j.issn.1007-7812.201911017
中图分类号：
学科分类号：
摘要：
The developments of amplification methods of nitrogen chains in energetic material synthesis were reviewed. The common reactions such as substitution reactions of N-X bonds by azido groups, electro-catalytic oxidation reactions of azide ions, diazo transfer reactions of primary amines, dimerization reactions of diimine, N-amination and nitration reactions, oxidative coupling reactions of amine groups, and diazo-coupling reactions of amine groups were summarized. The mechanisms of typical amplification reactions of nitrogen chains were also introduced. The structural evolution processes of ionic nitrogen chains such as N5+, [N7O]+, N8-, and organic compounds with all-nitrogen fragments such as N3/N4/N5/N6/N7/N8/N10/N11 chains were emphatically discussed. The possible synthetic routes of N7-, N10 and N12 chains and the development trends of this research field were pointed out. With 65 references. © 2021, Editorial Board of Journal of Explosives & Propellants. All right reserved.
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页码：21 / 29
页数：8
相关论文
共 64 条
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